A low-temperature (90 °C) and directly grown anatase titanium dioxide (TiO2) nanocrystalline film using successive ionic layer adsorption and reaction (SILAR) for perovskite solar cell and gas sensor applications. TiO2 nanocrystalline electron transfer layer (ETL) improves the power conversion efficiency (PCE) of perovskite solar cells due to faster charge transport kinetics as well as slower charge recombination process. The optimized TiO2 nanocrystalline ETL (15 L) demonstrates as high as ~10% PCE with a short circuit current density of 18.0 mA/cm2, open circuit voltage of 0.81 V and fill factor of 66.3% in perovskite solar cells. Furthermore, room-temperature ammonia sensing characteristics of TiO2 nanocrystalline film (25 L) were demonstrated for various concentration levels of ammonia in dry air conditions. A high room-temperature response of 80% was achieved at 100 ppm of ammonia with rapid response and recovery signatures of 30 and 85 s, and nearly fifteen days stability, respectively. The response of the sensor to other gases such as formaldehyde, petrol, ethanol acetone, and ammonia etc, indicated a high selectivity towards volatile organic compounds of ammonia gas. The room temperature operation, with high selectivity, repeatability and fast transition times, suggests potentially useful in flexible and cost-effective production in optoelectrochemical device technology.
Carbonized sugar (CS) has been synthesized via microwave-assisted carbonization of market-quality tabletop sugar bearing in mind the advantages of this synthesis method, such as being useful, cost-effective, and eco-friendly. The as-prepared CS has been characterized for its morphology, phase purity, type of porosity, pore-size distribution, and so on. The gas-sensing properties of CS for various oxidizing and reducing gases are demonstrated at ambient temperature, where we observe good selectivity toward liquid ammonia among other gases. The highest ammonia response (50%) of a CS-based sensor was noted at 80 °C for 100 ppm concentration. The response and recovery times of the CS sensor are 180 and 216 s, respectively. This unveiling ammonia-sensing study is explored through a plausible theoretical mechanism, which is further well-supported by computational modeling performed using density function theory. The effect of relative humidity on the CS sensor has also been studied at ambient temperature, which demonstrated that the minimum and maximum (20-100%) relative humidity values revealed 16 and 62% response, respectively.
Graphene oxide catalyst, obtained by table sugar carbonization, is envisaged for the synthesis of bio-active benzylpyrazolyl coumarin derivatives with considerable yield and remarkable re-usability.
Successive ion transfer synthesis, efficient chemoresistive gas sensing and asymmetric electrochemical supercapacitive properties of Bi2O3 nanostructures are unveiled.
A promising electrode for hydrogen evolution reaction (HER) has been prepared via a reduction process to form NiF2 nanorod arrays directly grown on a 3D nickel foam.
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