The He(!) photoelectron spectra of the title compounds have been measured. An empirical assignment of most of the bands is proposed and the effects of various substituents on the phosphorus lone-pair ionisation potentials are assessed. Correlations are made with various other parameters relating to phosphine basicity, and it is concluded that the phosphorus lone-pair i.p. provides a reasonable measure of relative basicity or 6donor ability within related series of compounds.of Sussex, Brighton BN1 9QJ
A lysimeter experiment was carried out on a relatively infertile soil to examine the effect of potassium fertiliser application on the uptake of radiocaesium by spring wheat. Porous ceramic cups were used to obtain samples of soil solution. Results showed that the uptake of radiocaesium by spring wheat was reduced by the addition of potassium. However this inhibitory effect was less marked at later stages of plant growth due to factors such as the spatial variability of potassium within the soil, differences in root distribution down the soil profile and age-related demand for potassium by the plant. There was some evidence that a negative power function could be used to describe the relationship between the concentration of 137Cs in the plant and concentrations of potassium or 137Cs:K quotients in soil solution over the whole experimental period. Practical implications of potassium fertilisation in terms of reducing uptake of radiocaesium by crops are discussed.
Concentrations of a range of naturally occurring radionuclides have been determined in the same crops grown at two sites in the UK. Ovine liver has also been studied. One site was in an area where concentrations in soil are typical of the UK (the 'control' site) and the other in an area where levels were well above average (the 'test' site). For an average adult consumer of all of the foodstuffs studied, the doses from consumption for the test site were about 4 times higher than those for the control site. However, the differences were small compared with the variability in overall doses from natural background across the UK. 210Pb and 210Po were important contributors to doses for both sites, but at the test site the contribution from 226Ra was also significant. Of the foodstuffs studied, consumption of leafy vegetables and liver gave the highest doses. The doses from leafy vegetables were sensitive to the weather conditions prior to harvesting. Consequently, rigorous monitoring programmes should be based on several samples collected throughout the year; extrapolations based on a single annual sample are unlikely to be reliable.
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