The chemical composition of cooperage oak wood is highly variable, depending upon the tree species (Quercus robur L. versus Quercus petraea Liebl.), its geographic location, and the single-tree effect. In the process of cask-making, natural seasoning and toasting contribute strongly to the modification of the oak wood chemical composition and therefore influence wine cooperaging. HPLC and GC quantification of ellagitannins and volatile compounds such as whiskey-lactones, eugenol, and vanillin over a sample set of 61 pedunculate oaks and 72 sessile oaks originating from six different forests showed that natural drying leads to a decrease of the ellagitannins and total extractives content level and a quasi constant level of the volatile compounds. Toasting (medium type) drastically enhanced the loss of ellagitannins and the gain in volatile compounds. Statistical treatment showed that the species effect remained significant throughout the process of drying and toasting, but not the provenance. The poor correlation with ring width of extractives levels measured on fresh timber remained unchanged as did the single-tree effect, with high variability found for all chemical parameters. These results provide further evidence that cooperage oak selection should not be based solely on the wood grain or the provenance but rather on a species-provenance combination.
SummaryThe low field1H NMR relaxometry technique has been shown to be effective in determining the qualitative and quantitative moisture content and the water state distribution in maritime pine wood (Pinus pinasterAit). Further investigations on extractive materials in resin-rich samples evinced the presence of oleoresin components, which may disturb adhesion on pine wood boards.
ABSTRACT:The present study concerns the investigation of a material expected to be biocompatible and able to promote bone regeneration. For this purpose, cellulose was chemically modified by phosphorylation. Once implanted, phosphorylated cellulose could promote the formation of calcium phosphates, thus having closer resemblance to bone functionality. In a previous investigation, the obtention and the preliminary characterization of cellulose phosphate gels were reported. In the present study, the synthesis by the H 3 PO 4 /P 2 O 5 /Et 3 PO 4 /hexanol method was optimized in terms of reaction parameters. The structure of materials was investigated by FTIR, Raman, and solid-state 31 P-and 13 C-NMR spectroscopic studies, and X-ray diffraction. Water swelling and stability to sterilization by gamma-radiation were also assessed. It was demonstrated that the present method allows highly phosphorylated cellulose derivatives to be obtained. Cellulose triphosphates gels are described here for the first time. Products obtained were poorly crystallized monoesters, apparently not significantly affected by gamma sterilization and showed a high water swelling capability. Chemical bonding was confirmed by FTIR, Raman, and both 31 P-and 13 C-NMR spectroscopies. It was also shown that the H 3 PO 4 / P 2 O 5 /Et 3 PO 4 /hexanol method provides a versatile and interesting alternative route to some of the more widely used techniques for the phosphorylation of cellulose.
An amino-silicone in the form of a micro- and a macro-emulsion (average particle size 40 and 120 nm, respectively) was tested in impregnation of solid wood. During vacuum-pressure impregnation, the uptake of 5% emulsions was only slightly reduced compared to water up-take. At 15% concentration, a significant reduction in emulsion uptake was observed, particularly in the radial and tangential directions of the wood. The penetration of silicone into the cell wall was dependent on the particle size of the emulsion. Applied as a macro-emulsion, a maximum of only 14% of the total silicone penetrated the cell wall, whereas 25–35% of the silicone was found in the cell wall when applied as a micro-emulsion. The degree of cell wall penetration of silicone for the micro-emulsion was confirmed by X-ray micro-analysis (SEM-EDX). The penetrated silicone caused bulking and dimensional stability. 1H NMR relaxometry T
2 distributions were determined for dried and moisture-conditioned wood samples. The silicone-treated specimens displayed spin-spin interactions of protons from water and silicones (or their emulsifiers). Conditioning of samples at 25°C and 65% relative humidity appeared to cause a decrease in the mobility of the non-water protons of the silicone and/or emulsifier. Freezing to -5°C caused separation of protons from bound water and from the silicone at low relaxation times. It is assumed that treatment with the micro-emulsion reduced water sorption due to micro-pore blocking in the cell wall. The formation of a sandwich complex is postulated, which comprises cell wall polymers, water molecules and a layer of silicone.
Abstract. Dry extract, ellagitanins, free ellagic acid, whisky-lactone, eugenol and vanillin have been quantified for a sample set of 61 pedunculate oaks (Quercus robur L.) and 72 sessile oaks (Quercus petraea Liebl.) originating from 6 different forests. Despite a very high interindividual variability, pedunculate oak shows higher level of dry extract, ellagitanins and free ellagic acid but lower level in volatil compounds compared to sessile oak. Inside a same species, differences between forests are less marked. Extractible compounds level is poorly correlated to the grain (ring width). Regarding cambial age, it might have its significance but lack of scientific data could not permit to conclude in that sense. Our results suggest that cooperage oak selection should be based on a species-provenance combination rather than on the grain or the provenance solely.
The chemical modification of maritime pine sapwood (Pinus pinaster) with alkoxysilanes was studied according to three different pathways: carbamoylation with 3isocyanatopropyltriethoxysilane, etherification with 3glycidoxypropyltrimethoxysilane and alcoholysis of n-propyltrimethoxysilane. Grafting was confirmed by weight percent gain calculations (WPG), infrared spectroscopy (FTIR) as well as 13 C and 29 Si NMR CP MAS analysis. Signals of the grafted groups in the different spectra were assigned and the reactivity of the trialkoxysilane moieties towards wood was discussed. Experiments with model wood blocks showed that the reactions investigated occurred within the wood cell walls. Grafted chemicals were found to be relatively stable with regard to water leaching but only slight dimensional stabilisation was noted after treatment.
The time domain of 1 H NMR spectroscopy allows straightforward editing of the T 2 relaxation profiles in maritime pine wood. A new method from the Carr-Purcell-Meiboom-Gill sequence is proposed to measure the amount and distribution of water in wood, as well as the location of major dissolved organic materials. A general calibration model giving reliable and precise identification of these parameters is described. The method presented for editing T 2 relaxation profiles (obtained by the Contin program) may be helpful in solving practical drying and gluing problems in the wood industry. It can be used for monitoring chemical modifications of wood fibers involved in the design of wood composite materials.
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