The total internal reflection ellipsometry (TIRE) method was used for the excitation and study of the sensitivity properties of the hybrid Tamm plasmon polariton – surface plasmon polariton (TPP-SPP) and single surface plasmon resonance (SPR) modes of the GCSF receptor immobilization. Additionally, the optimized sensitivity of the hybrid TPP-SPP mode was investigated and compared with the single SPR mode when the BSA proteins formed a layer on the gold surface. The dispersion relations for the hybrid TPP-SPP and single SPR modes were used to explain the enhanced sensitivity of the ellipsometric parameters for the hybrid TPP-SPP mode over the conventional SPR. The SPP component (δΔh-SPP/δλ=53.9°/nm) of the hybrid TPP-SPP mode was about 6.4 times more sensitive than single SPR (δΔSPR/δλ=8.4°/nm) for the BSA protein layer on the gold film. It was found that the sensitivity of the hybrid plasmonic mode can be made controllable by using the strong coupling effect between the TPP and SPP components. The strong coupling regime reduces absorption and scattering losses of the metal for the SPP component in the hybrid TPP-SPP mode and, as a result, narrows the plasmonic resonance.
The total internal refection ellipsometry (TIRE) method was used for the generation and study of the hybrid TPP-SPP mode on a photonic crystal structure with a thin layer of silver and graphene/PMMA. Raman spectroscopy showed a consistent monolayer graphene present on the Ag layer. Recent studies have also shown that TPP and SPP components in the hybrid plasmonic mode is sensitive to the variation of coupling strength due to presence of the graphene monolayer. The decrease of the TPP and SPP dip components in the TPP-SPP hybrid mode can be explained by the changes of the conductivity of the silver layer due to the presence of this additional graphene/PMMA structure, which results in the non-optimal resonance conditions for the hybrid plasmonic mode. The modified positions of the TPP and SPP components in the wavelength spectra when compared to their original, separate excitations, indicates a strong coupling regime. The design of these hybrid plasmonic/graphene-based nanostructures has attractive capabilities for the development of advanced optical sensors and integrated optical circuit technologies.
There is increasing interest in the design of films with thicknesses on the order of 10 nm and less for a variety of applications, such as nanoparticles, plasmonics, quantum dots, solar reflectors, black mirrors, etc. The indices of refraction ( n and k ) for the effective media of such coatings depend on the materials with which such “layers” interface and the specific process parameters used to produce those films. The structures may typically be nucleating island structures and may also be continuous films. A key factor is that the n and k values vary in thickness until some thickness is obtained, usually > 20 n m . Heretofore, to the best of our knowledge, films have not taken into account thickness index variations during the design process. Software has now been developed where the index at a given thickness is computed at each iteration of the design optimization process. This allows more realistic design results utilizing the full representation of the behavior of the layers in question; the resulting coatings, when produced, are in better agreement with the designs. Including n and k versus wavelength and thickness in the design process is here referred to as double dispersion.
Low-cost 1D plasmonic photonic structures supporting Tamm plasmon polaritons and cavity modes were employed for optical signal enhancement, modifying the commercially available quartz crystal microbalance with dissipation (QCM-D) sensor chip in a combinatorial spectroscopic ellipsometry and quartz microbalance method. The Tamm plasmon optical state and cavity mode (CM) for the modified mQCM-D sample obtained sensitivity of ellipsometric parameters to RIU of ΨTPP = 126.78 RIU−1 and ΔTPP = 325 RIU−1, and ΨCM = 264 RIU−1 and ΔCM = 645 RIU‑1, respectively. This study shows that Tamm plasmon and cavity modes exhibit about 23 and 49 times better performance of ellipsometric parameters, respectively, for refractive index sensing than standard spectroscopic ellipsometry on a QCM-D sensor chip. It should be noted that for the optical biosensing signal readout, the sensitivity of Tamm plasmon polaritons and cavity modes are comparable with and higher than the standard QCM-D sensor chip. The different origin of Tamm plasmon polaritons (TPP) and cavity mode (CM) provides further advances and can determine whether the surface (TPP) or bulk process (CM) is dominating. The dispersion relation feature of TPP, namely the direct excitation without an additional coupler, allows the possibility to enhance the optical signal on the sensing surface. To the best of our knowledge, this is the first study and application of the TPP and CM in the combinatorial SE-QCM-D method for the enhanced readout of ellipsometric parameters.
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