N-Aryl amides were synthesized via the manganese-mediated amidation of esters with nitroarenes without the need for additional catalysts or ligands.

A 105-day experimental trial was conducted to assess different levels of dietary Aleo vera extract supplementation on water quality parameters, proximate composition, growth performance and haematological parameters of fry Oreochromis niloticus. Four different percentages of dietary leaf extract powder of Aleo vera (ALE) with a basal feed, designated as, i.e., T0 (Control group; without ALE), T1 (1% ALE), T2 (2% ALE), and T3 (3% ALE). Fish fry was reared in concrete tanks (7.0 m, 1.6 m, 1.0: L, W, H; water volume 11.2 m3/tank), with an average initial weight 4.04 ± 0.03 g/ fry, and each treatment was triplicated. Fry was randomly distributed at a stocking rate of 450 individuals/ tanks. The water quality parameters revealed that temperature, pH, salinity, dissolved oxygen (DO) and nitrates were found in a promising range as given by FAO/WHO limits. However, the record values obtained for Electric Conductivity (EC), Total dissolved solids (TDS), and alkalinities were not found in all tanks' suitable range according to FAO/WHO limits. The results revealed a significant impact of different percentages of dietary ALE supplementation on fry's body composition and haematological parameters. Moreover, the final body weight, final body length, average daily weight gain (g), net weight gain (g) and specific growth rate (%) were significantly higher (p < 0.05) in T1 and T2 compared with T0 and T3 treatments. The poorest feed conversion ratio was recorded in the T2 group compared with other treatments. Thus, the current study provides information about the nutritional quality of Nile tilapia culturing in Pakistan.

This project aims to investigate the most important weak interaction nuclei in the presupernova evolution of massive stars. To achieve this goal, an ensemble containing 728 nuclei in the mass range of A = 1–100 was considered. We computed the mass fractions of these nuclei using Saha’s equation for predetermined values of T, ρ, and Y e and assuming nuclear statistical equilibrium. The nuclear partition functions were obtained using a newly introduced recipe where excited states, up to 10 MeV, were treated as discrete. The weak interaction rates (electron capture (ec) and β-decay (bd)) were calculated in a totally microscopic fashion using the proton–neutron quasiparticle random phase approximation model and without assuming the Brink–Axel hypothesis. The calculated rates were coupled with the computed mass fractions to investigate the time rate of change of lepton to baryon fraction of the stellar matter. We compare our results with the previous calculations reported in the literature. Noticeable differences up to orders of magnitude are reported with previous calculations. These differences may influence the evolution of the star in the later stages of presupernova. We present a list of the top 50 ec and bd nuclei, which have the largest effect on Y e for conditions after silicon core burning. The competition between the ec and bd rates in the stellar core was investigated and it was found that Y e = 0.424–0.455 is the interval where the bd results are bigger than the ec rates.