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Agricultural soils can act as a potential sink of the increased carbon dioxide in the atmosphere if managed properly by application of organic manures and balanced fertilizers. However, the rate of carbon (C) sequestration in soils is low in warm climates and thus the short term changes in soil organic carbon (SOC) contents are almost negligible. Therefore, the knowledge about other C fractions that are more sensitive or responsive and indicative of the early changes in SOC can help to determine the effect of the management practices on soil C sequestration. The objective of this study was to determine the soil C sequestration after 16-years of applications of chemical fertilizers and farmyard manure (FYM) to rice (Oryza sativa)-cowpea (Vigna unguiculata) rotation system in a sandy loam soil (Typic Rhodalfs). The treatments were-(1) one control (no fertilizer or FYM); (2) three chemical fertilizer treatments [100 kg N ha -1 (N), 100 kg N ha -1 ? 50 kg P 2 O 5 ha -1 (NP), 100 kg N ha -1 ? 50 kg P 2 O 5 ha -1 ? 50 kg K 2 O ha -1 (NPK)]; (3) one integrated treatment [(50 kg N ha -1 ? 25 kg P 2 O 5 ha -1 ? 25 K 2 O ha -1 ) ? (50 kg N ha -1 from FYM)]; and (4) one organic treatment at10 Mg ha -1 FYM. Compared to the control treatment, the increase in SOC was 36, 33, and 19% greater in organic, integrated, and NPK treatments. The 16-years application of fertilizers and/or FYM resulted in much greater changes in water soluble C (WSC), microbial biomass C (MBC), light fraction of C (LFC), and particulate organic matter (POM) than SOC. Of the SOC, the proportion of POM was highest (24-35%), which was followed by LFC (12-14%), MBC (4.6-6.6%), and WSC (0.6-0.8%). The application of fertilizers and/or FYM increased the mean weight diameter of soil aggregates; thus provided physical protection to SOC from decomposition. Our results suggests that the application of fertilizers and/or FYM helps to sequester C in the soil and that the labile fractions of C can be used as indicators to determine the amount of C sequestered as a result of different management practices.

Abstract. Knowledge about the scaling properties of soil water storage is crucial in transferring locally measured fluctuations to larger scales and vice-versa. Studies based on remotely sensed data have shown that the variability in surface soil water has clear scaling properties (i.e., statistically self similar) over a wider range of spatial scales. However, the scaling property of soil water storage to a certain depth at a field scale is not well understood. The major challenges in scaling analysis for soil water are the presence of localized trends and nonstationarities in the spatial series. The objective of this study was to characterize scaling properties of soil water storage variability through multifractal detrended fluctuation analysis (MFDFA). A field experiment was conducted in a sub-humid climate at Alvena, Saskatchewan, Canada. A north-south transect of 624-m long was established on a rolling landscape. Soil water storage was monitored weekly between 2002 and 2005 at 104 locations along the transect. The spatial scaling property of the surface 0 to 40 cm depth was characterized using the MFDFA technique for six of the soil water content series (all gravimetrically determined) representing soil water storage after snowmelt, rainfall, and evapotranspiration. For the studied transect, scaling properties of soil water storage are different between drier periods and wet periods. It also appears that local controls such as site topography and texture (that dominantly control the pattern during wet states) results in multiscaling property. The nonlocal controls such as evapotranspiration results in the reduction of the degree of multiscaling and improvement in the simple scaling. Therefore, the scaling property of soil water storage is a function of both soil moisture status and the spatial extent considered.

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