Coherent superposition of light from subwavelength sources is an attractive prospect for the manipulation of the direction, shape and polarization of optical beams. This phenomenon constitutes the basis of phased arrays, commonly used at microwave and radio frequencies. Here we propose a new concept for phased-array sources at infrared frequencies based on metamaterial nanocavities coupled to a highly nonlinear semiconductor heterostructure. Optical pumping of the nanocavity induces a localized, phase-locked, nonlinear resonant polarization that acts as a source feed for a higher-order resonance of the nanocavity. Varying the nanocavity design enables the production of beams with arbitrary shape and polarization. As an example, we demonstrate two second harmonic phased-array sources that perform two optical functions at the second harmonic wavelength (∼5 μm): a beam splitter and a polarizing beam splitter. Proper design of the nanocavity and nonlinear heterostructure will enable such phased arrays to span most of the infrared spectrum.

Natural gas based hydrogen production with carbon capture and storage is referred to as blue hydrogen.

Methane (CH4) emissions from oil and natural gas (O&NG) systems are an important contributor to greenhouse gas emissions. In the United States, recent synthesis studies of field measurements of CH4 emissions at different spatial scales are ~1.5–2× greater compared to official greenhouse gas inventory (GHGI) estimates, with the production-segment as the dominant contributor to this divergence. Based on an updated synthesis of measurements from component-level field studies, we develop a new inventory-based model for CH4 emissions, for the production-segment only, that agrees within error with recent syntheses of site-level field studies and allows for isolation of equipment-level contributions. We find that unintentional emissions from liquid storage tanks and other equipment leaks are the largest contributors to divergence with the GHGI. If our proposed method were adopted in the United States and other jurisdictions, inventory estimates could better guide CH4 mitigation policy priorities.

Methane, a key component of natural gas, is a potent greenhouse gas. A key feature of recent methane mitigation policies is the use of periodic leak detection surveys, typically done with optical gas imaging (OGI) technologies. The most common OGI technology is an infrared camera. In this work, we experimentally develop detection probability curves for OGI-based methane leak detection under different environmental and imaging conditions. Controlled single blind leak detection tests show that the median detection limit (50% detection likelihood) for FLIR-camera based OGI technology is about 20 g CH/h at an imaging distance of 6 m, an order of magnitude higher than previously reported estimates of 1.4 g CH/h. Furthermore, we show that median and 90% detection likelihood limit follows a power-law relationship with imaging distance. Finally, we demonstrate that real-world marginal effectiveness of methane mitigation through periodic surveys approaches zero as leak detection sensitivity improves. For example, a median detection limit of 100 g CH/h is sufficient to detect the maximum amount of leakage that is possible through periodic surveys. Policy makers should take note of these limits while designing equivalence metrics for next-generation leak detection technologies that can trade sensitivity for cost without affecting mitigation priorities.

Concerns over mitigating methane leakage from the natural gas system have become ever more prominent in recent years. Recently, the U.S. Environmental Protection Agency proposed regulations requiring use of optical gas imaging (OGI) technologies to identify and repair leaks. In this work, we develop an open-source predictive model to accurately simulate the most common OGI technology, passive infrared (IR) imaging. The model accurately reproduces IR images of controlled methane release field experiments as well as reported minimum detection limits. We show that imaging distance is the most important parameter affecting IR detection effectiveness. In a simulated well-site, over 80% of emissions can be detected from an imaging distance of 10 m. Also, the presence of "superemitters" greatly enhance the effectiveness of IR leak detection. The minimum detectable limits of this technology can be used to selectively target "superemitters", thereby providing a method for approximate leak-rate quantification. In addition, model results show that imaging backdrop controls IR imaging effectiveness: land-based detection against sky or low-emissivity backgrounds have higher detection efficiency compared to aerial measurements. Finally, we show that minimum IR detection thresholds can be significantly lower for gas compositions that include a significant fraction nonmethane hydrocarbons.

Introduction The recent Intergovernmental Panel on Climate Change (IPCC) special report on global warming of 1.5°C highlighted the importance of reducing short-lived greenhouse gases like methane (Intergovernmental Panel on Climate Change, 2018). Methane, a major component of natural gas, has a global warming potential that is 36 times that of carbon dioxide over a 100-year period (Myhre, et al., 2013), and even higher over shorter time periods (Etminan, Myhre, Highwood, & Shine, 2016). Furthermore, methane emissions contribute to sea-level rise over much longer timescales than their atmospheric lifetimes (Zickfeld, Solomon, & Gilford, 2017). These consequences are troubling given that official methane emissions inventory in the US and Canada have been found to be systematically underestimated (Alvarez, et al.,

Reducing methane emissions from the oil and gas industry is a critical climate action policy tool in Canada and the US. Optical gas imaging-based leak detection and repair (LDAR) surveys are commonly used to address fugitive methane emissions or leaks. Despite widespread use, there is little empirical measurement of the effectiveness of LDAR programs at reducing long-term leakage, especially over the scale of months to years. In this study, we measure the effectiveness of LDAR surveys by quantifying emissions at 36 unconventional liquids-rich natural gas facilities in Alberta, Canada. A representative subset of these 36 facilities were visited twice by the same detection team: an initial survey and a post-repair re-survey occurring ∼0.5-2 years after the initial survey. Overall, total emissions reduced by 44% after one LDAR survey, combining a reduction in fugitive emissions of 22% and vented emissions by 47%. Furthermore, >90% of the leaks found in the initial survey were not emitting in the re-survey, suggesting high repair effectiveness. However, fugitive emissions reduced by only 22% because of new leaks that occurred between the surveys. This indicates a need for frequent, effective, and low-cost LDAR surveys to target new leaks. The large reduction in vent emissions is associated with potentially stochastic changes to tank-related emissions, which contributed ∼45% of all emissions. Our data suggest a key role for tank-specific abatement strategies as an effective way to reduce oil and gas methane emissions. Finally, mitigation policies will also benefit from more definitive classification of leaks and vents.

We present a tool for modeling the performance of methane leak detection and repair programs that can be used to evaluate the effectiveness of detection technologies and proposed mitigation policies. The tool uses a two-state Markov model to simulate the evolution of methane leakage from an artificial natural gas field. Leaks are created stochastically, drawing from the current understanding of the frequency and size distributions at production facilities. Various leak detection and repair programs can be simulated to determine the rate at which each would identify and repair leaks. Integrating the methane leakage over time enables a meaningful comparison between technologies, using both economic and environmental metrics. We simulate four existing or proposed detection technologies: flame ionization detection, manual infrared camera, automated infrared drone, and distributed detectors. Comparing these four technologies, we found that over 80% of simulated leakage could be mitigated with a positive net present value, although the maximum benefit is realized by selectively targeting larger leaks. Our results show that low-cost leak detection programs can rely on high-cost technology, as long as it is applied in a way that allows for rapid detection of large leaks. Any strategy to reduce leakage should require a careful consideration of the differences between low-cost technologies and low-cost programs.