In this paper, we evaluated the ecotoxicological potential of the 100 pharmaceuticals expected to occur in highest quantities in the wastewater of a general hospital and a psychiatric center in Switzerland. We related the toxicity data to predicted concentrations in different wastewater streams to assess the overall risk potential for different scenarios, including conventional biological pretreatment in the hospital and urine source separation. The concentrations in wastewater were estimated with pharmaceutical usage information provided by the hospitals and literature data on human excretion into feces and urine. Environmental concentrations in the effluents of the exposure scenarios were predicted by estimating dilution in sewers and with literature data on elimination during wastewater treatment. Effect assessment was performed using quantitative structure-activity relationships because experimental ecotoxicity data were only available for less than 20% of the 100 pharmaceuticals with expected highest loads. As many pharmaceuticals are acids or bases, a correction for the speciation was implemented in the toxicity prediction model. The lists of Top-100 pharmaceuticals were distinctly different between the two hospital types with only 37 pharmaceuticals overlapping in both datasets. 31 Pharmaceuticals in the general hospital and 42 pharmaceuticals in the psychiatric center had a risk quotient above 0.01 and thus contributed to the mixture risk quotient. However, together they constituted only 14% (hospital) and 30% (psychiatry) of the load of pharmaceuticals. Hence, medical consumption data alone are insufficient predictors of environmental risk. The risk quotients were dominated by amiodarone, ritonavir, clotrimazole, and diclofenac. Only diclofenac is well researched in ecotoxicology, while amiodarone, ritonavir, and clotrimazole have no or very limited experimental fate or toxicity data available. The presented computational analysis thus helps setting priorities for further testing. Separate treatment of hospital wastewater would reduce the pharmaceutical load of wastewater treatment plants, and the risk from the newly identified priority pharmaceuticals. However, because high-risk pharmaceuticals are excreted mainly with feces, urine source separation is not a viable option for reducing the risk potential from hospital wastewater, while a sorption step could be beneficial.

We quantify the technical and environmental performance of clean hydrogen production (with CCS) by linking detailed process simulation with LCA.

Natural gas based hydrogen production with carbon capture and storage is referred to as blue hydrogen.

Direct air carbon capture and storage (DACCS) is an emerging carbon dioxide removal technology, which has the potential to remove large amounts of CO2 from the atmosphere. We present a comprehensive life cycle assessment of different DACCS systems with low-carbon electricity and heat sources required for the CO2 capture process, both stand-alone and grid-connected system configurations. The results demonstrate negative greenhouse gas (GHG) emissions for all eight selected locations and five system layouts, with the highest GHG removal potential in countries with low-carbon electricity supply and waste heat usage (up to 97%). Autonomous system layouts prove to be a promising alternative, with a GHG removal efficiency of 79–91%, at locations with high solar irradiation to avoid the consumption of fossil fuel-based grid electricity and heat. The analysis of environmental burdens other than GHG emissions shows some trade-offs associated with CO2 removal, especially land transformation for system layouts with photovoltaics (PV) electricity supply. The sensitivity analysis reveals the importance of selecting appropriate locations for grid-coupled system layouts since the deployment of DACCS at geographic locations with CO2-intensive grid electricity mixes leads to net GHG emissions instead of GHG removal today.

Purpose Representative, consistent and up-to-date life cycle inventories (LCI) of electricity supply are key elements of ecoinvent as an LCI background database since these are often among the determining factors with regard to life cycle assessment (LCA) results. ecoinvent version 3 (ev3) offers new LCI data of power supply (electricity markets) in 71 geographies. This article gives an overview of these electricity markets and discusses new ecoinvent features in the context of power supply. Methods The annual geography-and technology-specific electricity production for the year 2008 specifies the technology shares on the high-, medium-and low-voltage level electricity markets. Data are based on IEA statistics. Different voltage levels are linked by transformation activities. Regionspecific electricity losses due to power transmission and voltage transformation are considered in the market and transformation activities. The majority of the 71 power markets are defined by national boundaries. The attributional ecoinvent system model in ev3 with linking to average current suppliers results in electricity markets supplied by all geographyspecific power generation technologies and electricity imports, while the consequential system model generates markets only linked to unconstrained suppliers. Results and discussionThe availability of LCI data for 71 electricity markets in ev3 covering 50 countries reduces the "Rest-of-the-World" electricity supply not covered by country-or region-specific inventories to 17 % for the year 2008. Specific power supply activities for all countries contributing more than 1 % to global electricity production are available. The electricity markets show large variations concerning contributions from specific technologies and energy carriers. Imports can substantially change the national/ regional power mix, especially in small markets. Large differences can also be observed between the electricity markets in the attributional and the consequential database calculation. Region-specific total power losses between production on the high voltage level and consumer on the low voltage level are on the order of 2.5-23 %. Conclusions Electricity supply mixes (electricity markets) in the ecoinvent database have been updated and substantially extended for v3. Inventories for electricity supply in all globally important economies are available with geographyspecific technology and market datasets which will contribute to increasing quality and reducing uncertainties in LCA studies worldwide and to allow more accurate estimation of environmental burdens from global production chains. Future work should focus on improving the details of countryspecific data, implementation of more countries into the database, splitting of large countries into smaller regions and on developing a more sophisticated approach specifying countryspecific electricity mixes in consequential system models.

Purpose The long-term marginal electricity supply mixes of 40 countries were generated and integrated into version 3.4 of the ecoinvent consequential database. The total electricity production originating from these countries accounts for 77% of the current global electricity generation. The goal of this article is to provide an overview of the methodology used to calculate the marginal mixes and to evaluate the influence of key parameters and methodological choices on the results. Methods The marginal mixes are based on public energy projections from national and international authorities and reflect the accumulated effect of changes in demand for electricity on the installation and operation of new-generation capacities. These newly generated marginal mixes are first examined in terms of their compositions and environmental impacts. They are then compared to several sets of alternative electricity supply mixes calculated using different methodological choices or data sources. Results and discussion Renewable energy sources (RES) as well as natural gas power plants show the highest growth rates and usually dominate the marginal mixes. Nevertheless, important variations may exist between the marginal mixes of the different countries in terms of their technological compositions and environmental impacts. The examination of the modeling choices reveals substantial variations between the marginal mixes integrated into the ecoinvent consequential database version 3.4 and marginal mixes generated using alternative modeling options. These different modeling possibilities include changes in the methodology, temporal parameters, and the underlying energy scenarios. Furthermore, in most of the impact categories, average (i.e., attributional) mixes cause higher impact scores than marginal mixes due to higher shares of RES in marginal mixes. Conclusions Accurate and consistent data for electricity supply is integrated into a consequential database providing a strong basis for the development of consequential Life Cycle Assessments. The methodology adopted in this version of the database eliminates several shortcomings from the previous approach which led to unrealistic marginal mixes in several countries. The use of energy scenarios allows the evolution of the electricity system to be considered within the definition of the marginal mixes. The modeling choices behind the electricity marginal mix should be adjusted to the goal and scope of individual studies and their influence on the results evaluated. Keywords CLCA. Ecoinvent. Life cycle inventory (LCI) database. Long-term marginal electricity supply mix 1 Using the IPCC Global Warming Potentials (GWP) characterization factors with a time horizon of 100 years and the calculation approach detailed in Mutel (2018).

Purpose Life cycle inventories (LCI) of electricity generation and supply are among the main determining factors regarding life cycle assessment (LCA) results. Therefore, consistency and representativeness of these data are crucial. The electricity sector has been updated and substantially extended for ecoinvent version 3 (v3). This article provides an overview of the electricity production datasets and insights into key aspects of these v3 inventories, highlights changes and describes new features.Methods Methods involved extraction of data and analysis from several publically accessible databases and statistics, as well as from the LCA literature. Depending on the power generation technology, either plant-specific or regionspecific average data have been used for creating the new power generation inventories representing specific geographies. Whenever possible, the parent-child relationship was used between global and local activities. All datasets include a specific technology level in order to support marginal mixes used in the consequential version of ecoinvent. The use of parameters, variables and mathematical relations enhances transparency. The article focuses on documentation of LCI data on the unlinked unit process level and presents direct emission data of the electricity-generating activities.Results and discussion Datasets for electricity production in 71 geographic regions (geographies) covering 50 countries are available in ecoinvent v3. The number of geographies exceeds the number of countries due to partitioning of power generation in the USA and Canada into several regions. All important technologies representing fossil, renewable and nuclear power are modelled for all geographies. The new inventory data show significant geography-specific variations: thermal power plant efficiencies, direct air pollutant emissions as well as annual yields of photovoltaic and wind power plants will have significant impacts on cumulative inventories. In general, the power plants operating in the 18 newly implemented countries (compared to ecoinvent v2) are on a lower technology level with lower efficiencies and higher emissions. The importance of local datasets is once more highlighted. Conclusions Inventories for average technology-specific electricity production in all globally important economies are now available with geography-specific technology datasets. This improved coverage of power generation representing 83 % of global electricity production in 2008 will increase the quality of and reduce uncertainties in LCA studies worldwide and contribute to a more accurate estimation of environmental burdens from global production chains. Future work on LCI of electricity production should focus on updates of the fuel chain and infrastructure datasets, on including new technologies as well as on refining of the local data.

The use of biomass as a resource for hydrogen production can contribute to the transition towards carbon neutral or carbon negative energy systems. This paper offers a comprehensive investigation of...