The potential of precision spectroscopy as a tool in systematic searches for effects of Lorentz and CPT violation is investigated. Systems considered include hydrogen, antihydrogen, deuterium, positronium, and hydrogen molecules and molecular ions. Perturbative shifts in energy levels and key transition frequencies are derived, allowing for Lorentz-violating operators of arbitrary mass dimensions. Observable effects are deduced from various direct measurements, sidereal and annual variations, comparisons among species, and gravitational responses. We use existing data to place new and improved constraints on nonrelativistic coefficients for Lorentz and CPT violation, and we provide estimates for the future attainable reach in direct spectroscopy of the various systems or tests with hydrogen and deuterium masers. The results reveal prospective sensitivities to many coefficients unmeasured to date, along with potential improvements of a billionfold or more over certain existing results.

The prospects are explored for testing Lorentz and CPT symmetry in the muon sector via the spectroscopy of muonium and various muonic atoms, and via measurements of the anomalous magnetic moments of the muon and antimuon. The effects of Lorentz-violating operators of both renormalizable and nonrenormalizable dimensions are included. We derive observable signals, extract first constraints from existing data on a variety of coefficients for Lorentz and CPT violation, and estimate sensitivities attainable in forthcoming experiments. The potential of Lorentz violation to resolve the proton radius puzzle and the muon anomaly discrepancy is discussed.

Clock-comparison experiments are among the sharpest existing tests of Lorentz symmetry in matter. We characterize signals in these experiments arising from modifications to electron or nucleon propagators and involving Lorentz-and CPT-violating operators of arbitrary mass dimension. The spectral frequencies of the atoms or ions used as clocks exhibit perturbative shifts that can depend on the constituent-particle properties and can display sidereal and annual variations in time. Adopting an independent-particle model for the electronic structure and the Schmidt model for the nucleus, we determine observables for a variety of clock-comparison experiments involving fountain clocks, comagnetometers, ion traps, lattice clocks, entangled states, and antimatter. The treatment demonstrates the complementarity of sensitivities to Lorentz and CPT violation among these different experimental techniques. It also permits the interpretation of some prior results in terms of bounds on nonminimal coefficients for Lorentz violation, including first constraints on nonminimal coefficients in the neutron sector. Estimates of attainable sensitivities in future analyses are provided. Two technical appendices collect relationships between spherical and cartesian coefficients for Lorentz violation and provide explicit transformations converting cartesian coefficients in a laboratory frame to the canonical Sun-centered frame.

This is an overview of recent publications on the prospects of searching for nonminimal Lorentz-violating effects in atomic spectroscopy experiments. The article discusses the differences in the signals for Lorentz violation in the presence of minimal and nonminimal operators and what systems are more sensitive to certain types of Lorentz-violating operators.

A brief overview of the prospects of testing Lorentz and CPT symmetry with antimatter experiments is presented. The models discussed are applicable to atomic spectroscopy experiments, Penning-trap experiments and gravitational tests. Comments about the sensitivity of the most recent antimatter experiments to the models reviewed here are included.This article is part of the Theo Murphy meeting issue 'Antiproton physics in the ELENA era'.

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The prospects of studying nonminimal operators for Lorentz violation using spectroscopy experiments with light atoms and muon spin-precession experiments are presented. Possible improvements on bounds on minimal and nonminimal operators for Lorentz violation are discussed.

This presentation discusses some of the signals for Lorentz violation potentially observable in atomic spectroscopy and clock-comparison experiments. The emphasis of the discussion is on how the angular-momentum quantum numbers of the states involved in the transition determine the properties of the possible sidereal variation of the transition frequency.