We report the coupling of free-space photons (vacuum wavelength of 830 nm) to surface plasmon modes of a silver nanowire. The launch of propagating plasmons, and the subsequent emission of photons, is selective and occurs only at ends and other discontinuities of the nanowire. In addition, we observe that the nanowires redirect the plasmons through turns of radii as small as 4 microm. We exploit the radiating nature of discontinuities to find a plasmon propagation length >3 +/- 1 microm. Finally, we observe that interwire plasmon coupling occurs for overlapping wires, demonstrating plasmon fan-out at subwavelength scales.

Protein folding occurs as a set of transitions between structural states within an energy landscape. An oversimplified view of the folding process emerges when transiently populated states are undetected because of limited instrumental resolution. Using force spectroscopy optimized for 1-μs resolution, we reexamined the unfolding of individual bacteriorhodopsin molecules in native lipid bilayers. The experimental data reveal the unfolding pathway in unprecedented detail. Numerous newly detected intermediates—many separated by as few as 2– 3 amino acids—exhibited complex dynamics, including frequent refolding and state occupancies of <10 μs. Equilibrium measurements between such states enabled the folding free-energy landscape to be deduced. These results sharpen the picture of the mechanical unfolding of membrane proteins and, more broadly, enable experimental access to previously obscured protein dynamics.

We report a novel strategy for the controlled synthesis of gold nanoparticles (AuNPs) with narrow size distribution (1.9 ± 0.4 nm) through NP nucleation and growth inside the cavity of a well-defined three-dimensional, shape-persistent organic molecular cage. Our results show that both a well-defined cage structure and pendant thioether groups pointing inside the cavity are essential for the AuNP synthesis.

Analysis of steady-state and transient photoconductivity measurements at room temperature performed on c-axis oriented GaN nanowires yielded estimates of free carrier concentration, drift mobility, surface band bending, and surface capture coefficient for electrons. Samples grown ͑unintentionally n-type͒ by nitrogen-plasma-assisted molecular beam epitaxy primarily from two separate growth runs were examined. The results revealed carrier concentration in the range of ͑3-6͒ ϫ 10 16 cm −3 for one growth run, roughly 5 ϫ 10 14 -1ϫ 10 15 cm −3 for the second, and drift mobility in the range of 500-700 cm 2 / ͑V s͒ for both. Nanowires were dispersed onto insulating substrates and contacted forming single-wire, two-terminal structures with typical electrode gaps of Ϸ3-5 m. When biased at 1 V bias and illuminated at 360 nm ͑3.6 mW/ cm 2 ͒ the thinner ͑Ϸ100 nm diameter͒ nanowires with the higher background doping showed an abrupt increase in photocurrent from 5 pA ͑noise level͒ to 0.1-1 A. Under the same conditions, thicker ͑151-320 nm͒ nanowires showed roughly ten times more photocurrent, with dark currents ranging from 2 nA to 1 A. With the light blocked, the dark current was restored in a few minutes for the thinner samples and an hour or more for the thicker ones. The samples with lower carrier concentration showed similar trends. Excitation in the 360-550 nm range produced substantially weaker photocurrent with comparable decay rates. Nanowire photoconductivity arises from a reduction in the depletion layer via photogenerated holes drifting to the surface and compensating ionized surface acceptors. Simulations yielded ͑dark͒ surface band bending in the vicinity of 0.2-0.3 V and capture coefficient in the range of 10 −23 -10 −19 cm 2 . Atomic layer deposition ͑ALD͒ was used to conformally deposit Ϸ10 nm of Al 2 O 3 on several devices. Photoconductivity, persistent photoconductivity, and subgap photoconductivity of the coated nanowires were increased in all cases. TaN ALD coatings showed a reduced effect compared to the Al 2 O 3 coated samples.

Biomass exhibits a complex microstructure of directional pores that impact how heat and mass are transferred within biomass particles during conversion processes. However, models of biomass particles used in simulations of conversion processes typically employ oversimplified geometries such as spheres and cylinders and neglect intraparticle microstructure. Here we develop 3D models of biomass particles with size, morphology, and microstructure based on parameters obtained from quantitative image analysis. We obtain measurements of particle size and morphology by analyzing large ensembles of particles that result from typical size reduction methods, and we delineate several representative size classes. Microstructural parameters, including cell wall thickness and cell lumen dimensions, are measured directly from micrographs of sectioned biomass. A general constructive solid geometry algorithm is presented that produces models of biomass particles based on these measurements. Next, we employ the parameters obtained from image analysis to construct models of three different particle size classes from two different feedstocks representing a hardwood poplar species (Populus tremuloides, quaking aspen) and a softwood pine (Pinus taeda, loblolly pine). Finally, we demonstrate the utility of the models and the effects explicit microstructure by performing finiteelement simulations of intraparticle heat and mass transfer, and the results are compared to similar simulations using traditional simplified geometries. We show how the behavior of particle models with more realistic morphology and explicit microstructure departs from that of spherical models in simulations of transport phenomena and that species-dependent differences in microstructure impact simulation results in some cases.

We measure the J = 1 to J = 2 fine structure interval in the ( 3)2P state of helium to be 2 291 175.9(1.0) kHz. We use laser excitation of an atomic beam along with an integrated electro-optic modulator technique to obtain this result. The result is consistent (2.9+/-3.2 kHz) with what could be considered an earlier version of this experiment but is not in good agreement ( 20+/-5 kHz and 22+/-8 kHz) with the two other precision determinations of this interval. The current theoretical prediction lies between and overlaps the experiments.

We have demonstrated dramatic improvement in the quality of selective-area GaN nanowire growth by controlling the polarity of the underlying nucleation layers. In particular, we find that N-polarity is beneficial for the growth of large ordered nanowire arrays with arbitrary spacing. Herein, we present techniques for obtaining and characterizing polarity-controlled nucleation layers on Si (111) substrates. An initial AlN layer, which is demonstrated to adopt Al-(N-)polarity for N-(Al-)rich growth conditions, is utilized to configure the polarity of subsequently grown GaN layers as determined by piezoresponse force microscopy (PFM), polarity-dependent surface reconstructions, and polarity-sensitive etching. Polarity-dependent surface reconstructions observed in reflection high-energy electron diffraction (RHEED) patterns were found to be particularly useful for in situ verification of the nucleation layer polarity, prior to mask deposition, patterning, and selective-area regrowth of the GaN NW arrays. N-polar templates produced fast-growing nanowires with vertical m-plane side walls and flat c-plane tips, while Gapolar templates produced slow-growing pyramidal structures bounded by (11̅ 02) r-planes. The selective-area nanowire growth process window, bounded by nonselective and no-growth conditions, was found to be substantially more relaxed for NW arrays grown on N-polar templates, allowing for long-range selectivity where the NW pitch far exceeds the Ga diffusion length.

Vertically aligned multiwall carbon nanotubes were grown by water-assisted chemical vapor deposition on a large-area lithium tantalate pyroelectric detector. The processing parameters are nominally identical to those by which others have achieved the "world's darkest substance" on a silicon substrate. The pyroelectric detector material, though a good candidate for such a coating, presents additional challenges and outcomes. After coating, a cycle of heating, electric field poling, and cooling was employed to restore the spontaneous polarization perpendicular to the detector electrodes. The detector responsivity is reported along with imaging as well as visible and infrared reflectance measurements of the detector and a silicon witness sample. We find that the detector responsivity is slightly compromised by the heat of processing and the coating properties are substrate dependent. However, it is possible to achieve nearly ideal values of detector reflectance uniformly less than 0.1% from 400 nm to 4 microm and less than 1% from 4 to 14 microm.