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It is observed that for a square planar Ni(II)-Schiff base complex of the general formula {Ni(II)L}, where L is {L: N,N'-bis(5-hydroxy-salicylidene)ethylenediamine}, when encapsulated in a supercage of zeolite Y the bulky guest complex adopts a non-planar geometry without disturbing the integrity of the zeolite framework. Detailed comparative characterization is carried out to understand the structural change of the guest complex as a result of steric and electronic interactions with the host framework. UV-Vis spectroscopic studies of the encapsulated and 'neat' complex show a significant blue shift in the d-d transition after encapsulation and the diamagnetic 'neat' complex exhibits paramagnetism after encapsulation. DFT studies of the Ni(II)-Schiff base complex have been carried out for different spin states in neat and encapsulated form and the UV-Vis spectra are simulated using TD-DFT to understand the observed spectra in detail.

Square planar Ni(ii)-Schiff base complexes when encapsulated in a supercage of zeolite Y have shown altered optical, magnetic properties and catalytic activities in comparison to their corresponding free states. Different characterization techniques like XRD analysis, SEM-EDX, AAS, FTIR, UV-Visible spectroscopy and magnetic studies as well as detailed theoretical studies altogether show the differences in the properties of complexes in free and encapsulated states. All these studies have suggested that the largest complex deviates by the maximum amount from its free-state properties and a fascinating correlation between the extent of deviation from molecular dimension and modified catalytic activity of encapsulated complexes is observed.

Planar palladium–Schiff base complexes are synthesized, maintaining the order of their molecular dimensions as PdL1 < PdL2 < PdL3 < PdL4 < PdL5 in free state, as well as encapsulated in zeolite Y, where L1: N , N ′-bis(salicylidene)ethylenediamine and L2, L3, L4, and L5 are derivatives of L1. All encapsulated complexes have shown better catalytic activity for the sulfoxidation of methyl phenyl sulfide in comparison to their homogeneous counter parts. These hybrid systems are characterized with the help of different characterization techniques such as X-ray diffraction analysis, scanning electron microscopy–energy-dispersive X-ray spectrometry, X-ray photoelectron spectroscopy, Fourier transform infrared, and UV–visible spectroscopy; all of these studies have suggested that the largest complex deviates by the maximum from its free-state properties, and a radical change in the reactivity of the complex is observed.

On encapsulation inside the supercage of zeolite‐Y planar Cu (II)–Schiff base complexes show the modified structural, optical and functional properties. The electronic effect of the different substituent groups present in the catalyst plays the decisive role towards their reactivity in the homogeneous phase but after the encapsulation in zeolite Y, reactivity is mainly governed by the molecular dimensions of the guest complexes rather than the electronic factor of the substituent groups attached on them. These systems are well characterized with the help of different characterization tools like XRD analysis, SEM ‐ EDX, AAS, FTIR, XPS, DSC, TGA, BET and UV–Visible spectroscopy and the comparative optical and catalytic studies have provided a rational explanation of enhanced reactivity of zeolite encapsulated metal complexes for various oxidation reactions compared to their corresponding solution states.

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Purpose Using the extant literature review, this paper aims to explore the relationship between gender, entrepreneurial education (EE) and entrepreneurial intention (EI) in the Indian context, which the authors believe is a novel approach to this research stream. The authors also use career preparedness as a control variable to examine this relationship. Design/methodology/approach Data were collected from 368 undergraduate students across four Indian universities (one exclusively for female students) through a standard structured questionnaire. Additionally, rather than examining, EI has been treated as a monolithic construct; however, the authors conceptualize it as comprising three different dimensions that include grand vision and risk-taking ability; opportunity exploitation; and ability to persevere. An additional analysis was conducted for the students who reported higher scores for “being well prepared for their careers” through their institutes’ academic programs and communities of entrepreneurs. The authors also interviewed some entrepreneurship instructors, who confirmed the present findings through their observations. Findings The findings indicate that, essentially, there is a positive relationship between EE and EI. The authors find that male students scored higher for the first two dimensions of EI but not the third. Additionally, the authors used career preparedness as a control variable for additional analysis. The authors observed that students with higher “career preparedness” reported a positive relationship between EE and EI, independent of gender, for all three dimensions of EI. Thus, it may be assumed that if a community of entrepreneurs needs to be developed in India, a focus on career preparedness is critical. Research limitations/implications First, given that the present survey reflected a single moment in linking EE to EI (which may be considered a limitation of the study), future researchers might focus on a longitudinal approach. Second, all the respondents are attending urban universities (and, as such, very likely belong to the upper middle class of Indian society). The financial divide between urban and rural India is well known; as such, the results might be different if the sample was drawn from rural and poor India. Originality/value The salience/value of this study lies in the conceptualization of EI comprising three sub-constructs to understand the impact of formal EE (with three sub-constructs) on EI. The focus on career preparedness for a female student is a new direction of inquiry with respect to entrepreneurial intention.