High-energy
Li1.17Ni0.19Co0.10Mn0.54O2 (HE-NCM) is a lithium-rich layered
oxide with alternating Li- and transition-metal (TM) layers in which
excess lithium ions replace transition metals in the host structure.
HE-NCM offers a capacity roughly 50 mAh g–1 higher
compared to that of conventional layered oxides but suffers from capacity
loss and voltage fade upon cycling. Differential capacity plots (taken
over 100 cycles) show that the origin of the fading phenomenon is
a bulk issue rather than a surface degradation. Although previous
studies indicate only minor changes in the bulk material, long duration
in situ synchrotron X-ray powder diffraction measurements, in combination
with difference Fourier analysis of the data, revealed an irreversible
transition-metal motion within the host structure. The extensive work
provides new insights into the fading mechanism of the material.
TiNiSn is an intensively studied half-Heusler alloy that shows great potential for waste heat recovery. Here, we report on the structures and thermoelectric properties of a series of metal-rich TiNi1+ySn compositions prepared via solid-state reactions and hot pressing. A general relation between the amount of interstitial Ni and lattice parameter is determined from neutron powder diffraction. High-resolution synchrotron X-ray powder diffraction reveals the occurrence of strain broadening upon hot pressing, which is attributed to the metastable arrangement of interstitial Ni. Hall measurements confirm that interstitial Ni causes weak n-type doping and a reduction in carrier mobility, which limits the power factor to 2.5–3 mW m−1 K−2 for these samples. The thermal conductivity was modelled within the Callaway approximation and is quantitively linked to the amount of interstitial Ni, resulting in a predicted value of 12.7 W m−1 K−1 at 323 K for stoichiometric TiNiSn. Interstitial Ni leads to a reduction of the thermal band gap and moves the peak ZT = 0.4 to lower temperatures, thus offering the possibility to engineer a broad ZT plateau. This work adds further insight into the impact of small amounts of interstitial Ni on the thermal and electrical transport of TiNiSn.
The general concept of NMR crystallography is applied to the detailed study of calcium pyrophosphates (CPP), whether hydrated or not, and whether crystalline or amorphous. CPP are a fundamental family of materials among osteoarticular pathologic calcifications. Their prevalence increases with age, impacting on 17.5% of the population after the age of 80. They are frequently involved or associated with acute articular arthritis such as pseudogout. Current treatments are mainly directed at relieving the symptoms of joint inflammation but not at inhibiting CPP formation nor at dissolving these crystals. The combination of advanced NMR techniques, modeling and DFT based calculation of NMR parameters allows new original insights in the detailed structural description of this important class of biomaterials.
A new synchrotron X-ray powder diffraction instrument has been built and commissioned for long-duration experiments on beamline I11 at Diamond Light Source. The concept is unique, with design features to house multiple experiments running in parallel, in particular with specific stages for sample environments to study slow kinetic systems or processes. The instrument benefits from a high-brightness X-ray beam and a large area detector. Diffraction data from the commissioning work have shown that the objectives and criteria are met. Supported by two case studies, the results from months of measurements have demonstrated the viability of this large-scale instrument, which is the world's first dedicated facility for long-term studies (weeks to years) using synchrotron radiation.
Context. There is evidence to suggest that clathrate hydrates have a significant effect on the surface geology of icy bodies in the Solar System. However the aqueous environments believed to be present on these bodies are likely to be saline rather than pure water. Laboratory work to underpin the properties of clathrate hydrates in such environments is generally lacking. Aims. We aim to fill this gap by carrying out a laboratory investigation of the physical properties of CO 2 clathrate hydrates produced in weak aqueous solutions of MgSO 4 . Methods. We use in situ synchrotron X-ray powder diffraction to investigate clathrate hydrates formed at high CO 2 pressure in ice that has formed from aqueous solutions of MgSO 4 with varying concentrations. We measure the thermal expansion, density and dissociation properties of the clathrates under temperature conditions similar to those on icy Solar System bodies. Results. We find that the sulphate solution inhibits the formation of clathrates by lowering their dissociation temperatures. Hysteresis is found in the thermal expansion coefficients as the clathrates are cooled and heated; we attribute this to the presence of the salt in solution. We find the density derived from X-ray powder diffraction measurements is temperature and pressure dependent. When comparing the density of the CO 2 clathrates to that of the solution in which they were formed, we conclude that they should sink in the oceans in which they form. We also find that the polymorph of ice present at low temperatures is Ih rather than the expected Ic, which we tentatively attribute to the presence of the MgSO 4 . Conclusions. We (1) conclude that the density of the clathrates has implications for their behaviour in satellite oceans as their sinking and floating capabilities are temperature and pressure dependent, (2) conclude that the presence of MgSO 4 inhibits the formation of clathrates and in some cases may even affect their structure and (3) report the dominance of Ih throughout the experimental procedure despite Ic being the stable phase at low temperature.
A sample environment cell for long-duration X-ray diffraction studies of mineral precipitation in very slow cooling aqueous environments on Earth and other planetary bodies is described. The results are reported of a year-long commissioning experiment monitoring the dynamics of a freezing MgSO4–H2O solution at −28°C (245 K) in which meridianiite and epsomite are observed to form.
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