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A C C E P T E D M A N U S C R I P T ACCEPTED MANUSCRIPT
A C C E P T E D M A N U S C R I P T ACCEPTED MANUSCRIPT
AbstractPresent work is devoted to investigation of structure and functional properties of hybrid nanomaterials based on the TiO 2 -modified cellulose fibers of cotton. The titania hydrosol was successfully prepared using the titanium tetraisopropoxide as precursor and the nitric acid as peptizing agent via the low-temperature sol-gel synthesis in aqueous medium and applied to cotton fabric. For cross-linking of titania nanoparticles to cotton the 1,2,3,4-butanetetracarboxylic acid (BTCA) was used as a spacer. The morphology and composition of the surface pure and TiO 2 modified cotton fibers were investigated by the Scanning Electron Microscopy (SEM). The cotton/TiO 2 composite was characterized by the dielectric permittivity.For the estimation of total titania concentration, all samples were calcined at 650°C. The antimicrobial activity of the treated TiO 2 cotton fibers was investigated against Escherichia coli as a model Gram -negative bacteria after exposure to UV-irradiation for 10 minutes.
Abstract. The aim of this study was to evaluate new Zr-based bulk metallic composites with 11 crystallized dendrites or droplets which have the volume fraction below the critical one (the
Cu/AlN–Al2O3 nano-multilayer (NML) was deposited by magnetron sputtering method on 42CrMo4 steel samples, starting with a 15 nm AlN–Al2O3 layer and followed by 200 alternating layers of 5 nm thick Cu and 5 nm thick AlN–Al2O3 layers. The microstructure and thermal behaviour of the as-deposited and heat-treated multilayer was studied. Starting from about 400 °C, extensive coarsening of Cu nanocrystallites and the migration of Cu within the multilayer were observed via solid-state diffusion. Part of the initial Cu even formed micron-sized reservoirs within the NML. Due to increased temperature and to the different heat expansion coefficients of Cu and the AlN–Al2O3, the latter cracked and Cu appeared on the top surface of the NML at around 250 °C. Below 900 °C, the transport of Cu to the top surface of the NML probably took place as a solid-state flow, leading to faceted copper micro-crystals. However, above 900 °C, the Cu micro-crystals found on the top of the NML have rounded shape, so they were probably formed by pre-melting of nano-layered Cu due to its high specific surface area in the NML. Even if the Cu crystals appear on the top surface of the NML via solid-state flow without pre-melting, the Cu crystals on the top surface of the NML can be potentially used in joining applications at and above 250 °C.
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