We present the Pristine survey, a new narrow-band photometric survey focused on the metallicity-sensitive Ca H & K lines and conducted in the northern hemisphere with the wide-field imager MegaCam on the Canada-France-Hawaii Telescope (CFHT). This paper reviews our overall survey strategy and discusses the data processing and metallicity calibration. Additionally we review the application of these data to the main aims of the survey, which are to gather a large sample of the most metal-poor stars in the Galaxy, to further characterise the faintest Milky Way satellites, and to map the (metal-poor) substructure in the Galactic halo. The current Pristine footprint comprises over 1,000 deg 2 in the Galactic halo ranging from b ∼ 30 • to ∼ 78 • and covers many known stellar substructures. We demonstrate that, for SDSS stellar objects, we can calibrate the photometry at the 0.02-magnitude level. The comparison with existing spectroscopic metallicities from SDSS/SEGUE and LAMOST shows that, when combined with SDSS broad-band g and i photometry, we can use the CaHK photometry to infer photometric metallicities with an accuracy of ∼0.2 dex from [Fe/H] = −0.5 down to the extremely metal-poor regime ([Fe/H] < −3.0). After the removal of various contaminants, we can efficiently select metal-poor stars and build a very complete sample with high purity. The success rate of uncovering [Fe/H] SEGUE < −3.0 stars among [Fe/H] Pristine < −3.0 selected stars is 24% and 85% of the remaining candidates are still very metal poor ([Fe/H]< −2.0). We further demonstrate that Pristine is well suited to identify the very rare and pristine Galactic stars with [Fe/H] < −4.0, which can teach us valuable lessons about the early Universe. . The observations at the Canada-France-Hawaii Telescope were performed with care and respect from the summit of Maunakea which is a significant cultural and historic site.†

We use Gaia DR2 astrometric and photometric data, published radial velocities and MESA models to infer distances, orbits, surface gravities, and effective temperatures for all ultra metal-poor stars ([Fe/H] < −4.0 dex) available in the literature. Assuming that these stars are old (> 11 Gyr) and that they are expected to belong to the Milky Way halo, we find that these 42 stars (18 dwarf stars and 24 giants or sub-giants) are currently within ∼ 20 kpc of the Sun and that they map a wide variety of orbits. A large fraction of those stars remains confined to the inner parts of the halo and was likely formed or accreted early on in the history of the Milky Way, while others have larger apocentres (> 30 kpc), hinting at later accretion from dwarf galaxies. Of particular interest, we find evidence that a significant fraction of all known UMP stars (∼ 26%) are on prograde orbits confined within 3 kpc of the Milky Way plane (J z < 100 km s −1 kpc). One intriguing interpretation is that these stars belonged to the massive building block(s) of the proto-Milky Way that formed the backbone of the Milky Way disc. Alternatively, they might have formed in the early disc and have been dynamically heated, or have been brought into the Milky Way by one or more accretion events whose orbit was dragged into the plane by dynamical friction before disruption. The combination of the exquisite Gaia DR2 data and surveys of the very metal-poor sky opens an exciting era in which we can trace the very early formation of the Milky Way.

Context. The X-shooter Spectral Library (XSL) is an empirical stellar library at medium spectral resolution covering the wavelength range from 3000 Å to 24 800 Å. This library aims to provide a benchmark for stellar population studies. Aims. In this work, we present a uniform set of stellar atmospheric parameters, effective temperatures, surface gravities, and iron abundances for 754 spectra of 616 XSL stars. Methods. We used the full-spectrum fitting package ULySS with the empirical MILES library as reference to fit the ultraviolet-blue (UVB) and visible (VIS) spectra. We tested the internal consistency and we compared our results with compilations from the literature. Results. The stars cover a range of effective temperature 2900 < T eff < 38 000 K, surface gravity 0 < log g < 5.7, and iron abundance −2.5 < [Fe/H] < +1.0, with a couple of stars extending down to [Fe/H] = −3.9. The precisions of the measurements for the G-and K-type stars are 0.9%, 0.14, and 0.06 in T eff , log g, and [Fe/H], respectively. For the cool giants with log g < 1, the precisions are 2.1%, 0.21, and 0.22, and for the other cool stars these values are 1%, 0.14, and 0.10. For the hotter stars (T eff > 6500 K), these values are 2.6%, 0.20, and 0.10 for the three parameters.

The orbits of the least chemically enriched stars open a window on the formation of our Galaxy when it was still in its infancy. The common picture is that these lowmetallicity stars are distributed as an isotropic, pressure-supported component since these stars were either accreted from the early building blocks of the assembling Milky Way, or were later brought by the accretion of faint dwarf galaxies. Combining the metallicities and radial velocities from the Pristine and LAMOST surveys and Gaia DR2 parallaxes and proper motions for an unprecedented large and unbiased sample of very metal-poor stars at [Fe/H] ≤ −2.5 we show that this picture is incomplete. This sample shows strong statistical evidence (at the 5.0σ level) of asymmetry in their kinematics, favouring prograde motion. Moreover, we find that 31% of the stars that currently reside in the disk do not venture outside of the disk plane throughout their orbit. The discovery of this population implies that a significant fraction of stars with iron abundances [Fe/H] ≤ −2.5 formed within or concurrently with the Milky Way disk and that the history of the disk was quiet enough to allow them to retain their disk-like orbital properties.

The early Universe presented a star formation environment that was almost devoid of heavy elements. The lowest metallicity stars thus provide a unique window into the earliest Galactic stages, but are exceedingly rare and difficult to find. Here we present the discovery of an ultra-metal-poor star, Pristine 221.8781+9.7844, using narrow-band Ca H&K photometry from the Pristine survey. Follow-up medium and high-resolution spectroscopy confirms the ultra-metal-poor nature of Pristine 221.8781+9.7844 ([Fe/H] = −4.66 ± 0.13 in 1D LTE) with an enhancement of 0.3−0.4 dex in α-elements relative to Fe, and an unusually low carbon abundance. We derive an upper limit of A(C) = 5.6, well below typical A(C) values for such ultra metal-poor stars. This makes Pristine 221.8781+9.7844 one of the most metal-poor stars; in fact, it is very similar to the most metal-poor star known (SDSS J102915+172927). The existence of a class of ultra metal-poor stars with low(er) carbon abundances suggest that there must have been several formation channels in the early Universe through which long-lived, low-mass stars were formed.

We present the results of a 3-year long, medium-resolution spectroscopic campaign aimed at identifying very metal-poor stars from candidates selected with the CaHK, metallicity-sensitive Pristine survey. The catalogue consists of a total of 1007 stars, and includes 146 rediscoveries of metal-poor stars already presented in previous surveys, 707 new very metal-poor stars with [Fe/H] < −2.0, and 95 new extremely metal-poor stars with [Fe/H] < −3.0. We provide a spectroscopic [Fe/H] for every star in the catalogue, and [C/Fe] measurements for a subset of the stars (10% with [Fe/H] < −3 and 24% with −3 < [Fe/H] < −2) for which a carbon determination is possible, contingent mainly on the carbon abundance, effective temperature and S/N of the stellar spectra. We find an average carbon enhancement fraction ([C/Fe] ≥ +0.7) of 41 ± 4% for stars with −3 < [Fe/H] < −2 and 58 ± 14% for stars with [Fe/H] < −3, and report updated success rates for the Pristine survey of 56 % and 23 % to recover stars with [Fe/H] < −2.5 and [Fe/H] < −3, respectively. Finally, we discuss the current status of the survey and its preparation for providing targets to upcoming multi-object spectroscopic surveys such as WEAVE.

The Pristine survey uses narrow-band photometry to derive precise metallicities down to the extremely metal-poor regime ($ \rm [Fe/H] \lt -3$), and currently consists of over 4 million FGK-type stars over a sky area of $\sim 2500\, \mathrm{deg}^2$. We focus our analysis on a subsample of ∼80 000 main-sequence turn-off stars with heliocentric distances between 6 and 20 kpc, which we take to be a representative sample of the inner halo. The resulting metallicity distribution function (MDF) has a peak at $ \rm [Fe/H] =-1.6$, and a slope of Δ(LogN)/$\Delta \rm [Fe/H] = 1.0 \pm 0.1$ in the metallicity range of $-3.4\; \lt\; \rm [Fe/H]\; \lt -2.5$. This agrees well with a simple closed-box chemical enrichment model in this range, but is shallower than previous spectroscopic MDFs presented in the literature, suggesting that there may be a larger proportion of metal-poor stars in the inner halo than previously reported. We identify the Monoceros/TriAnd/ACS/EBS/A13 structure in metallicity space in a low-latitude field in the anticentre direction, and also discuss the possibility that the inner halo is dominated by a single, large merger event, but cannot strongly support or refute this idea with the current data. Finally, based on the MDF of field stars, we estimate the number of expected metal-poor globular clusters in the Milky Way halo to be 5.4 for $ \rm [Fe/H]\; \lt\; -2.5$ and 1.5 for $ \rm [Fe/H]\; \lt\; -3$, suggesting that the lack of low-metallicity globular clusters in the Milky Way is not due simply to statistical undersampling.

A chemo-dynamical analysis of 115 metal-poor candidate stars selected from the narrow-band Pristine photometric survey is presented based on CFHT highresolution ESPaDOnS spectroscopy. We have discover 28 new bright (V < 15) stars with [Fe/H]< −2.5 and 5 with [Fe/H]< −3.0 for success rates of 40% (28/70) and 19% (5/27), respectively. A detailed model atmospheres analysis is carried out for the 28 new metal-poor stars. Stellar parameters were determined from SDSS photometric colours, Gaia DR2 parallaxes, MESA/MIST stellar isochrones, and the initial Pristine survey metallicities, following a Bayesian inference method. Chemical abundances are determined for 10 elements (Na, Mg, Ca, Sc, Ti, Cr, Fe, Ni, Y, Ba). Most stars show chemical abundance patterns that are similar to the normal metal-poor stars in the Galactic halo; however, we also report the discoveries of a new r-process rich star, a new CEMP-s candidate with [Y/Ba]>0, and a metal-poor star with very low [Mg/Fe]. The kinematics and orbits for all of the highly probable metal-poor candidates are determined by combining our precision radial velocities with Gaia DR2 proper motions. Some stars show unusual kinematics for their chemistries, including planar orbits, unbound orbits, and highly elliptical orbits that plunge deeply into the Galactic bulge (R peri < 0.5 kpc); also, eight stars have orbital energies and actions consistent with the Gaia-Enceladus accretion event. This paper contributes to our understanding of the complex chemo-dynamics of the metal-poor Galaxy, and increases the number of known bright metal-poor stars available for detailed nucleosynthetic studies.