Background: Dengue virus type 1 (DENV-1) have been mostly circulating silently with dominant serotypes DENV-2 and DENV-3 in India. However recent times have marked an increase in DENV-1 circulation in yearly outbreaks. Many studies have not been carried out on this virus type, leaving a lacunae pertaining to the circulating genotypes, since its earliest report in India. In the present study, we sequenced CprM gene junction of 13 DENV-1 isolated from Delhi and Gwalior (North India) between 2001-2007 and one 1956 Vellore isolate as reference. For comparison, we retrieved 11 other Indian and 70 global reference sequences from NCBI database, making sure that Indian and global isolates from all decades are available for comparative analysis.
Quantification of the short-range order in amorphous silicon has been formulized using Raman scattering by taking into account established frameworks for studying the spectral line-shape and size dependent Raman peak shift. A theoretical line-shape function has been proposed for representing the observed Raman scattering spectrum from amorphous-Si-based on modified phonon confinement model framework. While analyzing modified phonon confinement model, the term "confinement size" used in the context of nanocrystalline Si was found analogous to the short-range order distance in a-Si thus enabling one to quantify the same using Raman scattering. Additionally, an empirical formula has been proposed using bond polarizability model for estimating the short-range order making one capable to quantify the distance of short-range order by looking at the Raman peak position alone. Both the proposals have been validated using three different data sets reported by three different research groups from a-Si samples prepared by three different methods making the analysis universal.
An "all-inorganic", fast, and power-efficient solid-state electrochromic device has been realized by choosing Co 3 O 4 and PB films as complementing electrodes. The prussian blue and cobalt oxide films have been synthesized via a simple galvanostatic method to achieve better film quality to be used in a device. Prior to fabricating a prototype solid-state device, the electrodes have been tested using in situ electrochemical and spectroscopic studies. This is followed by fabricating a solid-state device that shows switching between multiple colors with an applied bias of less than a couple of volts. A moderate color contrast of ∼40% with 1.5 s switching time has been observed with showing stability for more than 900 s of continuous switching. A redoxdriven electrochromic behavior of individual electrodes makes it possible for the solidstate device to show beautiful colors with a small applied bias. Electrochemical and spectroscopic measurements have been carried out to establish the possible mechanism of color switching shown by the device. Moreover, a coloration efficiency of ∼250 cm 2 /C makes it comparable to an "all-organic" or hybrid solid-state device, with its strong nature being an additional advantage.
A fast and flexible
all-organic electrochromic device, fabricated
using polythiophene and PCBM as active materials and plastic substrate,
which shows very good power efficiency as well, has been reported
here. The device shows quantifiable improvement in electrochromic
performance using parameters like switching speed, coloration efficiency,
color contrast, and cycle life. Spectroscopic investigations have
been carried out using Raman and UV–vis to establish a bias
induced redox switching based mechanism for the reported improvement
in the performance. The device shows switching between magenta (OFF)
and transparent states (ON) with a very small bias of ±1 V, an
optical modulation of 50% and an absorbance switching contrast of
91%. An enhanced stability for a duration of longer than 2500 s and
250 cycles has been reported with an ultrafast response of few hundred
milliseconds. A very high coloration efficiency of 321 cm2/C is achieved, making the proposed device one of the best reported
P3HT-based electrochromic devices.
The modern era is an era of science and technology that affects all aspects of life. The simplest physical manifestation of the term ‘technology’ takes place in the form of a simple and user-friendly device. The design and development of a smart device, capable of performing at its best, depends on the level of scientific understanding of the basic principles that make the actual backbone on which the technology relies. This leads to progressive development and research in electronics, materials science and related fields. An electrochromic device (ECD) is a perfect example of a smart yet very simple form of a device that can be useful for a range of applications, including electrochromism: the phenomenon of bias-induced optical modulation, shown primarily by at least one of the components in an ECD. This article attempts to provide an update on different materials’ regimes and highlights the basic requirements that a material must have to be suitable for use as the active component of an ECD. This topical review gives the details of several electrochromic materials, and their electrochemical, electrochromic and other functional properties in brief. An attempt has been made to cover a subset of the vast superset of known electrochromic materials, which can be extended as a detailed comprehensive review in the future. Based on the type(s) of materials used in an ECD, device paradigms are defined, which have also been summarized through different device regimes, namely ‘all-organic’, ‘all-inorganic’ and ‘hybrid’. A comparative study has also been provided by highlighting advantages and disadvantages of each category of material/device to help one choose a material and device paradigm based on one’s requirements. To provide a glimpse, ECDs that are multifunctional and that show other functionalities like memory, and supercapacitive and sensing characteristics have also been mentioned.
It is feared that the introduction of an independent lineage of the outbreak-associated strain of DENV-1 and its co-circulation with the deeply-rooted strain of DENV-3 in Delhi may result in yet another, possibly more severe outbreak in the near future.
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