The use of electron paramagnetic resonance spectroscopy to study the superoxide intermediates, generated by end-on and side-on adsorption of the naturally abundant and 17 O-enriched dioxygen on catalytic surfaces is discussed. Basic mechanisms of O 2 -radical formation via a cationic redox mechanism, an anionic redox mechanism, and an electroprotic mechanism are illustrated with selected oxide-based systems of catalytic relevance. Representative experimental spectra of various complexities are analyzed and their diagnostic features have been identified and interpreted. The molecular nature of the g and A tensors of the electrostatic and covalent superoxide adducts is discussed in detail within the classic and density functional theory based approaches.

The purpose of this study was to investigate a correlation between the spectroscopic and photophysical properties of Ru(II) polypyridyl complexes and their photodynamic activity in vitro. A series of Ru(II)...

A series of mixed cobalt spinel catalysts (MxCo3−xO4 (M = Cr, Fe, Mn, Ni, Cu, Zn)) was synthesized and tested in the CO-PROX reaction and in sole CO oxidation and H2 oxidation as references.

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