Cellulose nanofibers (CNFs) from banana peels was evaluated as promising stabilizer for oil-in-water emulsions. CNFs were treated using ultrasound and high-pressure homogenizer. Changes on the size, crystallinity index and zeta potential of CNFs were associated with the intense effects of cavitation phenomenon and shear forces promoted by mechanical treatments. CNFs-stabilized emulsions were produced under the same process conditions as the particles. Coalescence phenomenon was observed in the emulsions produced using high-pressure homogenizer, whereas droplets flocculation occurred in emulsions processed by ultrasound. In the latter, coalescence stability was associated with effects of cavitation forces acting on the CNFs breakup. Thus, smaller droplets created during the ultrasonication process could be recovered by particles that acted as an effective barrier against droplets coalescence. Our results improved understanding about the relationship between the choice of emulsification process and their effects on the CNFs properties influencing the potential application of CNFs as a food emulsifier.
a b s t r a c tThis work aimed to study the incorporation and preservation of gallic acid (GA) in emulsions formulated using soybean oil as oil phase, polyoxyethylene sorbitan (Tween 20) and polyglycerol polyricinoleate (PGPR) as surfactants. The systems evaluated were oil-in-water (O/W) and water-in-oil (W/O) emulsions prepared using the same aqueous to oily phases weight ratio (3:1). The volume fraction of surfactant was 0.01, 0.02 or 0.04 and gallic acid concentration in the final emulsions was 0 or 0.5% w/w. Increasing GA concentration did not show any effect on the initial or equilibrium interfacial tension (22 mN/m) in GA solution/soybean oil systems but reduced the average diameter of the droplets in both emulsions. The W/O emulsions showed bimodal droplet size distribution, pseudoplastic behavior and the presence of GA decreased the phase separation. The O/W emulsions exhibited kinetic stability, monomodal droplet size distribution and Newtonian fluid behavior. Results showed that the emulsification process was an efficient method to protect the bioactive against oxidation. Fresh O/W emulsions showed higher GA retention but during the storage time, the W/O emulsions showed a better capacity to retain the gallic acid. However, both emulsions exhibited high retention of bioactive (>86.61%) after 7 days of storage showing that this strategy could be used in different emulsified food products.
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