The effect of the use of TiO2 nanoparticles in the production of cementitious composites, worldwide already known, represents an area of interest for the development of materials with self-cleaning capacity; antimicrobial, antibacterial, antifungal properties; and to contribute to the reduction of environmental pollution. This paper aims to analyze the influence that TiO2 nanoparticles have on the cementitious matrix regarding hydrophilicity, this being one of the two main parameters of the self-cleaning mechanism. Experimental tests, conducted by using the indirect method of measuring the surface water absorption, indicated that an addition of 3%-6% (relative to the amount of cement) of TiO2 nanoparticles is effective in terms of increasing the surface hydrophilicity of the cementitious composites. An excess of TiO2 nanoparticles in the composite matrix (10% TiO2 nanoparticles relative to the amount of cement) not only does not improve surface performance in terms of hydrophilicity, but also reduces them. However, in practice on a case-by-case basis, an analysis is required regarding the optimal amount of nanoparticles used as an addition in the mix-design of the cementitious materials that are intended to induce the quality of self-cleaning process, depending on the intended use, climate, degree and duration of sunlight, and so on.
All industries produce wastes or byproducts, and if those are not properly managed, they will cause adverse effects on the environment. As the need for steel increases globally, waste from steel processing will also increase. Hazardous waste from steel processing is produced in the form of a coarse, dense aggregate, called steel slag. The aim of this paper is to present the possibility of using steel slag/blast furnace slag in the production of geopolymer concrete and to present the relevant results regarding the influence of this industrial byproduct on the mechanical properties of Geopolymer materials.
The aim of this paper is to propose ecological thermal insulation materials that meet the goals of sustainability but also fulfill the imposed thermal performance requirements. This paper studies new composite materials based on sheep wool from the perspective of thermal conductivity. The composites were prepared using two types of binder: acrylic-polyurethane resin and natural rubber latex, which were applied to the wool fibres through different methods and percentages. Based on the obtained results of thermal conductivity, two types of samples were selected for further analysis, which aimed to determine the microstructure, chemical composition, water absorption, attack of microorganisms, water vapour permeability, hygrothermal adsorption characteristics and sound absorption of the samples. In order to analyse the variation of thermal conductivity, the following parameters were taken into account: thickness, density, type of binder and percentage of binder. Following the obtained results, it was observed that the value of the thermal conductivity of the samples varies between 0.0324 and 0.0436 W/mK. It was found that all the samples prepared and analysed in this study fulfil the national criteria for the thermal performance of thermal insulation material. After conducting the in-depth analysis of the two selected sample types, it was concluded that both materials have good sound absorption characteristics over the considered frequency range. In addition, as it was expected from the natural fibres, the samples had low resistance against the attack of microorganisms and water-related tests.
The formation of biofilms on cementitious building surfaces can cause visible discoloration and premature deterioration, and it can also represent a potential health threat to building occupants. The use of embedded biofilm-resistant photoactivated TiO2 nanoparticles at low concentrations in the cementitious composite matrix is an effective method to increase material durability and reduce maintenance costs. Zone of inhibition studies of TiO2-infused cementitious samples showed efficacy toward both Gram-negative and Gram-positive bacteria.
Fibre Engineered Cementitious Materials (FECM) represent composites with similar overall performance as Engineered Cementitious Composites (ECC), namely developing strain hardening behaviour under loading, which generates the material capacity of high deformability. The pattern of multiple microcracks successively developed under increasing loading is proved to be the key of material self-consolidating potential and ability to support loads after the first crack occurrence. The matrix to fibre compatibility is considered to be one essential parameter controlling the multiple micro-cracking pattern (MC) and consequently, the strain hardening effect in the material. Factors like fibre type and reinforcement percent in the mixture represent sensitive variables, with major influence for matrix to fibre compatibility and overall performance of the composite. Cement based materials, whose compositional heterogeneity traditionally represents a lack in their regular usage, can be valorised and designed to produce the width controlled cracking typology, beneficial for material behaviour. This paper presents an experimental study on the fibre to matrix compatibility effect in the FECM design and producing process. Several types of dispersed reinforcing typologies for FECM development are experimentally tested and analysed. The results confirm the importance of matrix to fibre compatibility in enhancing superior material performance: physical, mechanical and even durability (Self-Healing potential evaluation).
Current research and development policies in the field of building materials, in the context of sustainable development, have the main objectives of increasing the safety and performance of the built environment at the same time as reducing pollution and its negative impact. Today, the idea that the sustainable city of the future should meet human needs and maintain a higher quality of life is worldwide unanimously accepted. The aim of this paper is to present results regarding the production of alkali-activated fly ash-based geopolymer concrete, a new, alternative material, produced using local available raw materials from Romania.
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