This work reports a new approach to extract the maximum chemical information from the absorption spectrum of extra virgin olive oils (EVOOs) in the 390-720 nm spectral range, where "oil pigments" dominate the light absorption. Four most important pigments, i.e., two carotenoids (lutein and β-carotene) and two chlorophylls (pheophytin-a and pheophytin-b), are chosen as reference oil pigments, being present in all the reported analytical data regarding pigments of EVOOs. The method allows the quantification of the concentration values of these four pigments directly from the deconvolution of the measured absorption spectrum of EVOOs. Advantages and limits of the method and the reliability of the pigment family quantification are discussed. The main point of this work is the description of a fast and simple method to extract of such information in less than a minute, through the mathematical analysis of the UV-vis spectrum of untreated samples of oil.
a b s t r a c tDeterministic optimization algorithms are very attractive when the objective function is computationally expensive and therefore the statistical analysis of the optimization outcomes becomes too expensive. Among deterministic methods, deterministic particle swarm optimization (DPSO) has several attractive characteristics such as the simplicity of the heuristics, the ease of implementation, and its often fairly remarkable effectiveness. The performances of DPSO depend on four main setting parameters: the number of swarm particles, their initialization, the set of coefficients defining the swarm behavior, and (for box-constrained optimization) the method to handle the box constraints. Here, a parametric study of DPSO is presented, with application to simulation-based design in ship hydrodynamics. The objective is the identification of the most promising setup for both synchronous and asynchronous implementations of DPSO. The analysis is performed under the assumption of limited computational resources and large computational burden of the objective function evaluation. The analysis is conducted using 100 analytical test functions (with dimensionality from two to fifty) and three performance criteria, varying the swarm size, initialization, coefficients, and the method for the box constraints, resulting in more than 40,000 optimizations. The most promising setup is applied to the hull-form optimization of a high speed catamaran, for resistance reduction in calm water and at fixed speed, using a potential-flow solver.
The paper is concerned with black-box nonlinear constrained multi-objective optimization problems. Our interest is the definition of a multi-objective deterministic partition-based algorithm. The main target of the proposed algorithm is the solution of a real ship hull optimization problem. To this purpose and in pursuit of an efficient method, we develop an hybrid algorithm by coupling a multi-objective DIRECT-type algorithm with an efficient derivative-free local algorithm. The results obtained on a set of "hard" nonlinear constrained multi-objective test problems show viability of the proposed approach. Results on a hull-form optimization of a high-speed catamaran (sailing in head waves in the North Pacific Ocean) are also presented. In order to consider a real ocean environment, stochastic sea state and speed are taken into account. The problem is formulated as a multi-objective optimization aimed at (i) the reduction of the expected value of the mean total resistance in irregular head waves, at variable speed and (ii) the increase of the ship operability, with respect to a set of motion-related constraints. We show that the hybrid method performs well also on this industrial problem.
The paper presents a study on four adaptive sampling methods of a multi-fidelity (MF) metamodel, based on stochastic radial basis functions (RBF), for global design optimisation based on expen-sive CFD computer simulations and adaptive grid refinement. The MF metamodel is built as the sum of a low-fidelity-trained metamodel and an error metamodel, based on the difference between high-and low-fidelity simulations. The MF metamodel is adaptively refined using dynamic sam-pling criteria, based on the prediction uncertainty in combination with the objective optimum and the computational cost of highand low-fidelity evaluations. The adaptive sampling methods are demonstrated by four analytical benchmark and two design optimisation problems, pertaining to the resistance reduction of a NACA hydrofoil and a destroyer-type vessel. The performance of the adaptive sampling methods is assessed via objective function convergence.
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