Cesius lead halide perovskite colloidal nanocrystals are among the most promising perovskite systems for light emitting devices applications, due to their high fluorescence quantum yield and high optical gain at room temperature. In this Letter, we report on the first investigation of the temperature dependence of the Amplified Spontaneous Emission (ASE) properties of thin films of CsPbBr 3 nanocrystals. We demonstrate that ASE is strongly temperature dependent, with a complex variation in temperature of the ASE intensity, threshold, and peak wavelength. The joint investigation of the photoluminescence (PL) spectra below and above the ASE threshold allows us to conclude that the temperature increase results in the formation of disordered sub-domains emitting in the low energy tail of the PL spectra, leading to the existence of three emission regimes with transitions at about 90 K and about 170 K, with individually different temperature dependences.

Metal halide perovskites are currently emerging as highly promising optoelectronic materials. It has been recently demonstrated that fully inorganic solution processed CsPbBr3 perovskite thin films show good electroluminescence properties combined with high thermal stability. In this work, we investigate in details the amplified spontaneous emission (ASE) properties of CsPbBr3 perovskite thin films, as a function of the temperature and the trap density, modified by changing the CsBr–PbBr2 precursor concentration. ASE is observed in samples from both CsBr-rich solution (low trap density) and equimolar solution (higher trap density), up to about 150 K, with a minimum threshold of 26 and 29 μJ cm–2 at 10 K, respectively. However, the different distribution of defect states, mainly above the first exciton level in the former and below it in the latter, strongly improved optical gain at 10 K and changed the ASE temperature dependence of CsBr-rich films.

We investigate the thickness dependence of the amplified spontaneous emission (ASE) threshold and operational lifetime in air-poly(9,9-dioctylfluorene)(PF8)-glass asymmetric active waveguides. We show that the ASE threshold decreases with the film thickness up to about 200 nm, and increases for higher thicknesses. The ASE operational lifetime increases with the thickness up to about 300 nm, and it is almost thickness independent for higher thickness. We show that the observed results are related to the guided mode confinement in the waveguide and to the spatial overlap between the guided modes and the excited region in the film.

The excellent optical and electronic properties of metal halide perovskites recently proposed these materials as interesting active materials for optoelectronic applications. In particular, the high color purity of perovskite colloidal nanocrystals (NCs) had recently motivated their exploration as active materials for light emitting diodes with tunable emission across the visible range. In this work, we investigated the emission properties of binary blends of conjugated polymers and perovskite NCs. We demonstrate that the emission color of the blends is determined by the superposition of the component photoluminescence spectra, allowing color tuning by acting on the blend relative composition. The use of two different polymers, two different perovskite NCs, and different blend compositions is exploited to tune the blend color in the blue-green, yellow-red, and blue-red ranges, including white light generation.

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Confocal Laser Scanning Microscopy (CLSM) has been used as a fast, user-friendly, and noninvasive tool for characterizing the phase composition differences at the substrate and air interfaces in thick films of polymer blends. A clearly different phase composition at the blend/glass interface and at the blend/air interface has been detected. We show that PCBM preferentially accumulates at the glass/blend interface, while P3HT preferentially accumulates at the blend/air interface, by comparing the integrated signal intensity of the luminescence coming from both interfaces. Our results demonstrate that CLSM can be used conveniently for the fast identification of a preferential phase segregation at interfaces in polymer blends. This is useful in the research field on devices (like sensors or planar waveguides) that are based on very thick layers (thickness higher than 1 μm).

Simultaneous photoluminescence (PL) and external quantum efficiency (EQE) confocal mapping is used to investigate the correlation between the local PL and the EQE in a regioregular poly(3-exylthiophene):poly(9,9-dioctylfluorene-co-benzothiadiazole) inverted bulk heterojunction solar cell. We show that the charge generation and charge collection are strongly non-uniform on a length scale up to 100 μm. Our results evidence that organic solar cells optimization requires not only the control of the submicrometric active materials arrangement but also the control of the large scale device uniformity.