0D transition metal phosphides (TMPs) nanocrystals (NCs)–2D ultrathin black phosphorus (BP) heterostructure (Ni2P@BP) have been synthesized via a facile sonication‐assisted exfoliation followed by a solvothermal process. Compared with the bare BP, the specially designed Ni2P@BP architecture can enhance the electrical conductivity (from 2.12 × 102 to 6.25 × 104 S m–1), tune the charge carrier concentration (from 1.25 × 1017 to 1.37 × 1020 cm–3), and reduce the thermal conductivity (from 44.5 to 7.69 W m–1 K–1) at 300 K, which can be considered for multiple applications. As a result, the Ni2P@BP exhibits excellent Li storage properties and high hydrogen evolution reaction electrocatalytic activities. The Ni2P@BP shows improved Li diffusion kinetics (e.g., the Li ions diffusion coefficient increases from 1.14 × 10–14 cm2 s–1 for pure BP nanosheets to 8.02 × 10–13 cm2 s–1 for Ni2P@BP). In addition, the Ni2P@BP electrode sustains hydrogen production with almost unchanged activity over 3000 cycles, which indicates its good chemical stability when operating under strong reducing environment.
The conceptual understanding of charge transport in conducting polymers is still ambiguous due to a wide range of paracrystallinity (disorder). Here, we advance this understanding by presenting the relationship between transport, electronic density of states and scattering parameter in conducting polymers. We show that the tail of the density of states possesses a Gaussian form confirmed by two-dimensional tight-binding model supported by Density Functional Theory and Molecular Dynamics simulations. Furthermore, by using the Boltzmann Transport Equation, we find that transport can be understood by the scattering parameter and the effective density of states. Our model aligns well with the experimental transport properties of a variety of conducting polymers; the scattering parameter affects electrical conductivity, carrier mobility, and Seebeck coefficient, while the effective density of states only affects the electrical conductivity. We hope our results advance the fundamental understanding of charge transport in conducting polymers to further enhance their performance in electronic applications.
Thermoelectric materials have the ability to convert heat energy to electrical power and vice versa. While the thermodynamic upper limit is defined by the Carnot efficiency, the material figure of merit, ZT is far from this theoretical limit, typically limited by a complex interplay of non-equilibrium charge and phonon scattering. Materials innovation is a slow, arduous process due to the complex correlations between crystal structure, microstructure engineering and thermoelectric properties. Many physical concepts and materials have been unearthed in this path to discovery, supported ably by innovations in technology over many decades, revealing important material and transport descriptors. In this review, we look back at some case studies of inorganic thermoelectric materials employing a birds-eye view of complementary advancements in scientific concepts and technological advancements and conclude that most high values of zT have emerged from new scientific ideas fueled by moderately mature technologies. Based on this conclusion, we then propose that the recent emergence of datadriven approaches and high throughput experiments, encompassing synthesis as well as characterization, with machine learning guided inverse design is perfectly suited to provide an accelerated pathway towards the discovery of next-generation thermoelectric materials, potentially providing a feasible alternative source of energy for a sustainable future.
Combining high‐throughput experiments with machine learning accelerates materials and process optimization toward user‐specified target properties. In this study, a rapid machine learning‐driven automated flow mixing setup with a high‐throughput drop‐casting system is introduced for thin film preparation, followed by fast characterization of proxy optical and target electrical properties that completes one cycle of learning with 160 unique samples in a single day, a >10× improvement relative to quantified, manual‐controlled baseline. Regio‐regular poly‐3‐hexylthiophene is combined with various types of carbon nanotubes, to identify the optimum composition and synthesis conditions to realize electrical conductivities as high as state‐of‐the‐art 1000 S cm−1. The results are subsequently verified and explained using offline high‐fidelity experiments. Graph‐based model selection strategies with classical regression that optimize among multi‐fidelity noisy input‐output measurements are introduced. These strategies present a robust machine‐learning driven high‐throughput experimental scheme that can be effectively applied to understand, optimize, and design new materials and composites.
Thermoelectric (TE) metal oxides overcome crucial disadvantages of traditional heavy-metal-alloy-based TE materials, such as toxicity, scarcity, and instability at high temperatures. Here, we report the TE properties of metal oxide superlattices, composed from alternating layers of 5% Pr 3+ -doped SrTiO 3−δ (SPTO) and 20% Nb 5+ -doped SrTiO 3−δ (STNO) fabricated using pulsed laser deposition (PLD). Excellent stability is established for these superlattices by maintaining the crystal structure and reproducing the TE properties after long-time (20 h) annealing at high temperature (∼1000 K). The introduction of oxygen vacancies as well as extrinsic dopants (Pr 3+ and Nb 5+ ), with different masses and ionic radii, at different lattice sites in SPTO and STNO layers, respectively, results in a substantial reduction of thermal conductivity via scattering a wider range of phonon spectrum without limiting the electrical transport and thermopower, leading to an enhancement in the figure-of-merit (ZT). The superlattice composed of 20 SPTO/STNO pairs, 8 unit cells of each layer, exhibits a ZT value of 0.46 at 1000 K, which is the highest among SrTiO 3 -based thermoelectrics. ■ INTRODUCTIONThe rapid increase in global energy consumption and the inability of conventional energy conversion technologies, such as combustion of fossil fuels, to reduce their negative impact on environment, have led to significant activities in developing alternative energy conversion technologies. One of these promising technologies is thermoelectrics (TE), which possesses sustainable, reliable, and scalable characteristics in converting waste heat into electricity. Currently, TE devices cannot replace the traditional power generation systems, because of their relatively low conversion efficiencies. The performance of TE materials is evaluated in terms of a dimensionless figure-of-merit (ZT), which is defined aswhere σ is the electrical conductivity, S is the Seebeck coefficient, T is the absolute temperature, and λ is the total thermal conductivity. 1 The total thermal conductivity consists of contributions from electronic (λ e ) and lattice (λ l ) thermal conductivities (i.e., λ = λ e + λ l ). Unfortunately, all of the physical quantities used to describe ZT are strongly correlated, which makes the enhancement of ZT extremely challenging. 2 The TE community has been intensively trying to achieve ZT ≥ 3 in order to make the performance of TE solid-state devices competitive with traditional energy conversion systems. Although heavy-metal-based alloys, such as SnSe (∼2.6) 3 and PbTe (∼2.2), 4 exhibit high ZT values, they are not attractive for a wide range of applications, because they are toxic, decomposable, and their constituents are not naturally abundant. For these reasons, metal oxides, which do not have the above-mentioned disadvantages of traditional TE materials, emerge as reasonable and viable alternatives. Among metal oxides, SrTiO 3 (STO) is a promising TE material, particularly at high temperatures, because it has a high melting point ...
Layered transition metal dichalcogenides (TMDCs) intercalated with alkali metals exhibit mixed metallic and semiconducting phases with variable fractions. Thermoelectric properties of such mixed-phase structure are of great interest because of the potential energy filtering effect, wherein interfacial energy barriers strongly scatter cold carriers rather than hot carriers, leading to enhanced Seebeck coefficient (S). Here, we study the thermoelectric properties of mixed-phase Li x MoS2 as a function of its phase composition tuned by in situ thermally driven deintercalation. We find that the sign of Seebeck coefficient changes from positive to negative during initial reduction of the 1T/1T′ phase fraction, indicating crossover from p- to n-type carrier conduction. These anomalous changes in Seebeck coefficient, which cannot be simply explained by the effect of deintercalation-induced reduction in carrier density, can be attributed to the hybrid electronic property of the mixed-phase Li x MoS2. Our work shows that careful phase engineering is a promising route toward achieving thermoelectric performance in TMDCs.
We demonstrate that the thermoelectric properties of highly oriented Al-doped zinc oxide (AZO) thin films can be improved by controlling their crystal orientation. The crystal orientation of the AZO films was changed by changing the temperature of the laser deposition process on LaAlO3 (100) substrates. The change in surface termination of the LaAlO3 substrate with temperature induces a change in AZO film orientation. The anisotropic nature of electrical conductivity and Seebeck coefficient of the AZO films showed a favored thermoelectric performance in c-axis oriented films. These films gave the highest power factor of 0.26 W m−1 K−1 at 740 K.
The discovery of novel materials for thermoelectric energy conversion has potential to be accelerated by data-driven screening combined with high-throughput calculations. One way to increase the efficacy of successfully choosing...
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