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Bulk nanobubbles are a novel nanoscale bubble system with unusual properties which challenge our understanding of bubble behavior. Because of their extraordinary longevity, their existence is still not widely accepted as they are often attributed to the presence of supramolecular structures or contaminants. Nonetheless, bulk nanobubbles are attracting increasing attention in the literature, but reports generally lack objective evidence that the observed nano-entities are indeed nanobubbles. In this paper, we use various physical and chemical analytical techniques to provide multiple evidence that the nano-entities produced mechanically in pure water by a continuous high-shear rotor-stator device or acoustic cavitation and spontaneously by water−ethanol mixing are indeed gas-filled domains. We estimate that the results presented here combined provide conclusive proof that bulk nanobubbles do exist and they are stable. This paper should help close the debate about the existence of bulk nanobubbles and, hence, enable the scientific community to rather focus on developing the missing fundamental science in this area.

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A new technique for generating bulk nanobubble suspensions has been developed based on Henry's law which states that the amount of dissolved gas in a liquid is proportional to its partial pressure above the liquid.

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Bacterial biofilms are a cause of contamination in a wide range of medical and biological areas. Ultrasound is a mechanical energy that can remove these biofilms using cavitation and acoustic streaming, which generates shear forces to disrupt biofilm from its surface. The aim of this narrative review is to investigate the literature on the mechanical removal of biofilm using acoustic cavitation to identify the different operating parameters affecting its removal using this method. The properties of the liquid and the properties of the ultrasound have a large impact on the type of cavitation generated. These include gas content, temperature, surface tension, frequency of ultrasound and acoustic pressure. Many of these parameters require more research to understand their mechanisms in the area of ultrasonic biofilm removal and further research will help to optimise this method for effective removal of biofilms from different surfaces.

We show that the mixing of organic solvents with pure water leads to the spontaneous formation of suspended nano-entities which exhibit long-term stability on the scale of months. A wide range of solvents representing different functional groups are studied: methanol, ethanol, propanol, acetone, DMSO and formamide. We use various physical and chemical analytical techniques to provide compounded evidence that the nano-entities observed in all these aqueous solvent solutions must be gas-filled nanobubbles as they cannot be attributed to solvent nanodroplets, impurities or contamination. The nanobubble suspensions are characterized in terms of their bubble size distribution, bubble number density and zeta potential. The bubble number density achieved is a function of the type of solvent. It increases sharply with solvent content, reaching a maximum at an intermediate solvent concentration, before falling off to zero. We show that, whilst bulk nanobubbles can exist in pure water, they cannot exist in pure organic solvents and they disappear at some organic solvent-water ratio depending on the type of solvent. The gas solubility of the solvent relative to water as well as the molecular structure of the solvent are determining factors in the formation and stability of bulk nanobubbles. These phenomena are discussed and interpreted in the light of the experimental results obtained.

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