This paper analyzes the ability of the SCG for briquettes production based on the use of xanthan gum as binder under low pressure and low temperature biomass manufacturing conditions. Briquettes were manufactured at room temperature, at 10, 15, 20, 25 and 30% of moisture content and 8, 10 and 12 MPa of compaction pressure. Raw SCG samples reached dry densities between 0.669 and 0.735 g/cm 3 for the samples with a moisture content of 15% and 8 MPa, and 10% and 12 MPa, respectively. Samples treated with 10% of xanthan gum got densities between 0.672 and 0.819 g/cm 3 depending on the moisture content and the compaction pressure. No one of the raw SCG combinations passed the durability test meanwhile xanthan ones with 30% of moisture content obtained the best results with a loss of mass of 9.1% for the combination compacted at 10 MPa. Raw SCG samples showed water absorption values between 0.498% and 0.846% meanwhile xanthan samples water absorption oscillated between 0.427% and 1.065%. Xanthan gum increased the SCG ashes content from 0.66% to 0.97% and decreased the Lower Heating Value (LHV) from 25,399 J/g of the pure raw SCG to 23,503 J/g. Thermogravimetric tests showed that xanthan gum mix compared to the raw SCG increased as well the volatile peak from 61.54 mW to 81.94 mW as the mass loss rate in the volatile stage from-0.0178 mg/s to-0.0184 mg/s.
The growing demand for cement has created a significant impact on the environment. Cement production requires huge energy consumptions; however, Pakistan is currently facing a severe energy crisis. Researchers are therefore engaged with the introduction of agricultural/industrial waste materials with cementitious properties to reduce not only cement production but also energy consumption, as well as helping protect the environment. This research aims to investigate the influence of binary cementitious material (BCM) on fresh and hardened concrete mixes prepared with metakaolin (MK) and ground granulated blast furnace slag (GGBFS) as a partial replacement of cement. The replacement proportions of BCM used were 0%, 5%, 10%, 15%, and 20% by weight of cement. A total of five mixes were prepared with 1 : 1.5 : 3 mix proportion at 0.54 water-cement ratios. A total of 255 concrete specimens were prepared to investigate the compressive, tensile, and flexural strength of concrete after 7, 28, and 56 days, respectively. It was perceived that the workability of concrete mixes decreased with an increasing percentage of MK and GGBFS. Also, the density and permeability of concrete decreased with an increasing quantity of BCM after 28 days. Conversely, the compressive, tensile, and flexural strength of concrete were enhanced by 12.28%, 9.33%, and 9.93%, respectively, at 10% of BCM after 28 days. The carbonation depth reduced with a rise in content of BCM (up to 10%) and then later improved after 28, 90, and 180 days. Moreover, the effect of chloride attack in concrete is reduced with the inclusion of BCM after 28 and 90 days. Similarly, the drying shrinkage of concrete decreased with an increase in the content of BCM after 40 days.
Changing human lifestyle and increasing urbanisation are contributory factors to the high demand for concrete construction materials across the globe. With the imminent developments in the unpopulated marine/coastal zones, higher installation of concrete facilities is still expected. However, poor design and construction procedures coupled with inadequate materials selection and exposure to aggressive environmental conditions, such as chloride laden environments, often result in the reduced aesthetic and structural performance of concrete. Deterioration of reinforced concrete structures located in a coastal/marine setting can influence the safety, economic, and sustainability aspects of society. Hence, there is an increased need for alternate binder systems with the ability to reduce the effects of chloride attack in concrete. This paper presents a critical review of the engineering properties of metakaolin (MK) based concrete exposed to chloride attack. The key advantages and limitations of using MK for concrete production purposes were outlined and evaluated. Areas for future research were also highlighted in this paper. Based on the favourable 28-day compressive strength (73–84 MPa) and durability performance documented across the numerous past year studies that were reviewed, it can be concluded that MK is a viable alternate binder material for combatting chloride attack in coastal/marine concrete structures. This, in conjunction with its lack of chemical CO2 emissions, proves that MK can be used to improve the serviceability and sustainability states of marine structures. The viewpoint of this review will guide concrete constructors and researchers on a possible framework for the utilisation of metakaolin for enhancing durability concrete in aggressive environments.
Small and medium‐sized enterprises (SMEs) are the main holders of the European economy and innovation projects are essential tools for SMEs to ensure their growth. A high percentage of innovation projects implemented by SMEs lacks planning and initial management, which causes the appearance of important problems for the SMEs survival.
The authors have confirmed with a field study of 72 Spanish small firms that a lot of these problems arise from an incomplete project definition, so it is necessary to help SMEs to have a specific methodology that is appropriate to their own characteristics and projects.
The statistical analysis shows how the project management knowledge helps to a better project definition, contributing to the project alignment with the company strategy. Also, it reveals other problems related to the project definition as planning, budget, market and financing.
Of this analysis, it concludes that the definition phase supports the other phases and is essential in order to achieve project success.
This paper presents an ‘integration model of factors’ that helps SMEs in the management of the definition phase of their innovation projects. This model relates the various areas of analysis needed to ensure their integration at the project definition.
The relationships between the different model areas have been defined, showing the way to integrate the technical, economic and strategic outlooks of project objectives management in the definition phase of the project.
This model has been implemented in 21 new innovation project definitions. The users' valuation has been very positive with a 90.4% of success and all of the model users are interested in implementing the model again in next projects. The main advantages highlighted were user‐friendliness, intuitive model and easy application.
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