Tissue materials development using 3D computational tools to predict the influence of the combination of different fibers can be employed in the design of innovative tissue products and furnish optimization. Fibrous materials can be designed using different 3D fiber models for each type of fibers, detailed to the point where the wall fiber thickness, fiber lumen, and collapse degree are considered and presented in this work. Eucalyptus, Pinus, and Picea kraft cellulose pulp fibers were selected because they are representative of differentiated fiber types. The fiber morphological measurements were obtained using two methods: one uses the fibers in suspension, without restraints, and the other uses a capillary fiber alignment. The results indicate good repeatability for both methods but differences of 14% for fiber length weighted in length, 2% for fiber width, 11% for coarseness, 35% for curl, and 88% for fines content. Scanning electron microscopy images were used to identify the fiber dimensions inside the tissue structure. Four different types of fiber models for eucalyptus fibers, with different fiber wall thickness and lumen dimensions, were presented and used to predict 3D computational fibrous structures.
Effects of enzymatic modification were evaluated in bleached Eucalyptus kraft and sulfite cellulosic pulps, separately, to improve key tissue paper properties and design new Eucalyptus fiber applications. Different cellulase dosages (0.01 mg and 0.1 mg of enzyme/g of pulp) and reaction times (30 min and 60 min) were used to modify the fibers and replace the traditional mechanical based refining or beating process. The results showed that for enzymatic modified kraft and sulfite pulps, the softness properties were improved by 1 and 2 units, respectively, for each unit of decreased strength properties. To achieve a balance between the tissue properties, the different fiber pulp furnishes that contained 80% of the enzymatically treated kraft pulp and 20% of the sulfite pulp with and without enzymatic treatment, were studied. Overall, the structures made with these mixtures presented softness properties in the commercial range (57.8 to 74.4), improved absorption properties (107 mm to 120 mm of capillary rise), and good strength properties (13.0 to 17.7 N.m/g). This study was conducted in order to adjust the fiber furnishes according to industrial tissue standards, using one Eucalyptus fiber type providing strength and another providing softness.
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