Two brilliant outcomes of supramolecular self-assembly directed, low molecular weight organic gelator based self-healable Co(II) and Ni(II) metallogels were achieved. The adipic acid as the low molecular weight organic gelator...

Aluminum (Al) is the third most abundant metal in earth crust, whose chemical form is mainly dependent on soil pH. The most toxic form of Al with respect to plants is Al3+, which exists in soil pH <5. Acidic soil significantly limits crop production mainly due to Al3+ toxicity worldwide, impacting approximately 50% of the world’s arable land (in North-Eastern India 80% soil are acidic). Al3+ toxicity in plants ensues root growth inhibition leading to less nutrient and water uptake impacting crop productivity as a whole. Rice is one of the chief grains which constitutes the staple food of two-third of the world population including India and is not untouched by Al3+ toxicity. Al contamination is a critical constraint to plant production in agricultural soils of North East India. 24 indigenous Indica rice varieties (including Badshahbhog as tolerant check and Mashuri as sensitive check) were screened for Al stress tolerance in hydroponic plant growth system. Results show marked difference in growth parameters (relative growth rate, Root tolerance index, fresh and dry weight of root) of rice seedlings due to Al (100 μM) toxicity. Al3+ uptake and lipid peroxidation level also increased concomitantly under Al treatment. Histochemical assay were also performed to elucidate uptake of aluminum, loss of membrane integrity and lipid peroxidation, which were found to be more in sensitive genotypes at higher Al concentration. This study revealed that aluminum toxicity is a serious harmful problem for rice crop productivity in acid soil. Based on various parameters studied it’s concluded that Disang is a comparatively tolerant variety whereas Joymati a sensitive variety. Western blot hybridization further strengthened the claim, as it demonstrated more accumulation of Glutathione reductase (GR) protein in Disang rice variety than Joymati under stressed condition. This study also observed that the emergence of lethal toxic symptoms occurs only after 48h irrespective of the dose used in the study.

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Using continuum elastic theory, we show that strain anisotropy removes the shape instability existing for an isotropically strained island. An anistropically strained island has always an anisotropic shape, elongating along the less-strained direction and adopting a narrow width in the more-strained direction. The sign of strain makes only a quantitative difference without changing the qualitative island shape. Our study establishes thermodynamic limits for growing nanowires with anisotropically strained islands.

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Key soil parameters, organic matter, soil pH and plant nutrients determine the capacity of a soil to sustain plant and animal productivity. Conservation agriculture (CA) and crop diversification or intensification may change these soil parameters positively or negatively, which eventually affect long-term sustainability. We monitored these key soil properties (at depths of 0–15 and 15–30 cm) under CA-based sustainable intensification practices: zero-till (ZT), and crop residue retention, and crop rotations on Inceptisols and Entisols in the Eastern Ganga Alluvial Plains from 2014 to 2017. The rainfall of this sub-tropical region is 1273–3201 mm. Soil organic carbon (C) ranged within 0.46–1.13% and generally followed (positive) rainfall gradients. At all sites, the soil under ZT tended to have higher organic C than conventional tillage (CT). Soil pHH2O ranged within 5.7–7.8 across the region. At all sites, soil pH generally decreased under ZT compared to CT. This was most marked at some acidic soil sites where pH decreased by up to 0.4 units; the lower the initial soil pH, the higher was the decrease in pH under ZT practice. In contrast, the reverse trend was observed for soil organic C. Partial nutrient balances for N, P and K in rice–wheat and rice–maize systems were positive for N and P (&lt;50 kg ha–1) but negative for K (up to 90 kg ha–1) under both tillage practices; more so under ZT practice even though crop residues were retained. Changes under ZT provide an opportunity to maintain soil organic C. However, remediation measures such as liming and efficient use of fertilisers are required for long-term sustainability of the farming systems in this agriculturally important region of South Asia.

Background:Many studies are there using adjuvants such as clonidine and fentanyl with bupivacaine in the subarachnoid block for prolonging postoperative analgesia. However, literature is divided regarding the dosage and efficacy of both intrathecal adjuvants. Furthermore, these adjuvants have their own side effects. Hence, search for ideal intrathecal adjuvant between clonidine and fentanyl to bupivacaine goes on.Aim:The aim of the present study was to compare the effect of intrathecal clonidine and fentanyl as adjuvant to bupivacaine in the subarachnoid block for lower limb orthopedic surgery.Materials and Methods:It was a prospective randomized study in which eighty patients posted for lower limb orthopedic surgery were divided into two groups of forty each. Group C – Received intrathecal hyperbaric bupivacaine (2.5 ml) +50 μg clonidine (diluted to 0.5 ml). Group F – Received intrathecal hyperbaric bupivacaine (2.5 ml) + fentanyl 25 μg (diluted to 0.5 ml). Duration of postoperative analgesia, sensory and motor block characteristics, hemodynamic parameters, and side effects were recorded and analyzed.Results:Time for first dose of rescue analgesic was delayed in Group C (510.84 ± 24.10 min) in comparison to Group F (434.95 ± 19.16 min) which was statistically significant (P < 0.001). Duration of sensory and motor block was significantly prolonged in Group C compared to Group F (P < 0.001). Sedation was more in Group C than Group F (P < 0.001). Other block characteristics, hemodynamic, and side effects were comparable in both groups.Conclusion:Intrathecal clonidine as adjuvant to hyperbaric bupivacaine provided prolonged postoperative analgesia with more sedation in comparison to intrathecal fentanyl.