Creating high-quality, low-resistance contacts is essential for the development of electronic applications using two-dimensional (2D) layered materials. Many previously reported methods for lowering the contact resistance rely on volatile chemistry that either oxidize or degrade in ambient air. Nearly all reported efforts have been conducted on only a few devices with mechanically exfoliated flakes which is not amenable to large scale manufacturing. In this work, Schottky barrier heights of metal-MoS2 contacts to devices fabricated from CVD synthesized MoS2 films were reduced by inserting a thin tunneling Ta2O5 layer between MoS2 and metal contacts. Schottky barrier height reductions directly correlate with exponential reductions in contact resistance. Over two hundred devices were tested and contact resistances extracted for large scale statistical analysis. As compared to metal-MoS2 Schottky contacts without an insulator layer, the specific contact resistivity has been lowered by up to 3 orders of magnitude and current values increased by 2 orders of magnitude over large area (>4 cm(2)) films.
We present a measurement technique, which we call the Pulsed Time-Domain Measurement, for characterizing hysteresis in carbon nanotube field-effect transistors, and demonstrate its applicability for a broad range of 1D and 2D nanomaterials beyond carbon nanotubes. The Pulsed Time-Domain Measurement enables the quantification (density, energy level, and spatial distribution) of charged traps responsible for hysteresis. A physics-based model of the charge trapping process for a carbon nanotube field-effect transistor is presented and experimentally validated using the Pulsed Time-Domain Measurement. Leveraging this model, we discover a source of traps (surface traps) unique to devices with low-dimensional channels such as carbon nanotubes and nanowires (beyond interface traps which exist in today's silicon field-effect transistors). The different charge trapping mechanisms for interface traps and surface traps are studied based on their temperature dependencies. Through these advances, we are able to quantify the interface trap density for carbon nanotube field-effect transistors (∼3 × 10(13) cm(-2) eV(-1) near midgap), and compare this against a range of previously studied dielectric/semiconductor interfaces.
A different mechanism was found for Cu transport through multi-transferred single-layer graphene serving as diffusion barriers on the basis of time-dependent dielectric breakdown tests. Vertical and lateral transport of Cu dominates at different stress electric field regimes. The classic E-model was modified to project quantitatively the effectiveness of the graphene Cu diffusion barrier at low electric field based on high-field accelerated stress data. The results are compared to industry-standard Cu diffusion barrier material TaN. 3.5 Å single-layer graphene shows the mean time-to-fail comparable to 4 nm TaN, while two-time and three-time transferred single-layer graphene stacks give 2× and 3× improvements, respectively, compared to single-layer graphene at a 0.5 MV/cm electric field. The influences of graphene grain boundaries on Cu vertical transport through the graphene layers are explored, revealing that large-grain (10-15 μm) single-layer graphene gives a 2 orders of magnitude longer lifetime than small-grain (2-3 μm) graphene. As a result, it is more effective to further enhance graphene barrier reliability by improving single-layer graphene quality through increasing grain sizes or using single-crystalline graphene than just by increasing thickness through multi-transfer. These results may also be applied for graphene as barriers for other metals.
Two-dimensional (2D) semiconductors have been proposed for heterogeneous integration with existing silicon technology, however their chemical vapor deposition (CVD) growth temperatures are often too high. Here, we demonstrate direct CVD solid source precursor synthesis of continuous monolayer (1L) MoS2 films at 560°C in 50-minutes, within the 450-to-600°C, 2-hour thermal budget window required for back-end-of-the-line (BEOL) compatibility with modern silicon technology. Transistor measurements reveal on-state current up to ~140 µA/µm at 1 V drain-to-source voltage for 100 nm channel lengths, the highest reported to date for 1L MoS2 grown below 600°C using solid source precursors. The effective mobility from transfer length method (TLM) test structures is 29 ± 5 cm 2 V -1 s -1 at 6.1 × 10 12 cm -2 electron density, which is comparable to mobilities reported from films grown at higher temperatures. The results of this work provide a path towards the realization of high quality, thermal-budget-compatible 2D semiconductors for heterogeneous integration with silicon manufacturing.
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