This review reports progress in solid electrolytes integrated into all-solid-state 2D and 3D lithium-ion microbatteries. The latest improvements, performance and challenges of the all-solid-state 2D and 3D structured microbatteries are analyzed.
This work reports the preparation of a three‐dimensional Si thin film negative electrode employing a porous Cu current collector. A previously reported copper etching procedure was modified to develop the porous structures inside a 9 μm thick copper foil. Magnetron sputtering was used for the deposition of an n‐type doped 400 nm thick amorphous Si thin film. Electrochemical cycling of the prepared anode confirmed the effectiveness of utilizing the approach. The designed Si thin film electrode retained a capacity of around 67 μAh cm−2 (1675 mAh g−1) in 100th cycle. The improved electrochemical performance resulted in an enhancement of both areal capacity and capacity retention in contrast with flat and rough current collectors that were prepared for comparison.
A novel three‐dimensionally (3D) ordered mesoporous polypyrrole (OMPPy) is successfully synthesized through a facile chemical polymerization using silica nanosphere arrays as hard templates. The resulting OMPPy possesses a large BET surface area (270.9 m2 g−1), 3D interconnected large mesopores (∼32 nm), and small mesopores (2‐4 nm) on the large mesopore walls. The OMPPy is then applied as a host to form a kind of sulfur/OMPPy (S/OMPPy) composite cathode through a solution method followed by a heat‐treatment process. Electrochemical test results show that the developed S/OMPPy cathode containing 51.1 wt% sulfur is able to deliver a high and stable specific discharge capacity of 908 mAh g−1 at 0.1C after 100 cycles. At higher discharge rates of 1C, the S/OMPPy exhibits a discharge capacity of 673.7 mAh g−1 after 100 cycles and 462.2 mAh g−1 after 300 cycles. The exceptional electrochemical performance of the S/OMPPy is attributed to the large surface area and the commendable pore size distribution of OMPPy for trapping polysulfides as well as the ordered large mesopores for excellent electrolyte accessibility and fast Li‐ion transport.
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