Many historically and culturally significant buildings have sandstones that contain swelling clay inclusions in the binding phase. Differential strains that evolve during wetting and drying cycles can generate stresses that are on the order of the strength of the stone, leading to degradation. Most damage observed in the field is surface delamination and buckling of the stone over a flaw, indicating that the damage is occurring during wetting. Classical buckling theory predicts buckling to occur at a particular aspect ratio, or flaw size. The results of this study confirm buckling theory experimentally. Through finite-element simulation and experiment, the study then explores a potential flaw propagation mechanism whereby nonuniform wetting patterns generate stress intensities capable of flaw propagation. As a result, small natural flaws can grow to the critical size necessary for buckling.
This paper introduces the Hard Soft Acid Base (HSAB) concept as a promising tool for the selection of gas sensing layers. Target gas molecule -sensitive layer tandems are discussed and interpreted in the terms of this theory. Sensing layers suitable for carbon dioxide, nitrogen dioxide, sulphur dioxide, and hydrogen sulphide detection are presented and classified according to this concept. For oxygen and mineral acids detection, an indirect HSAB approach is discussed. The paper explains how the HSAB principle can be useful in designing gas sensing layers for different types of sensing structures, such as: surface acoustic waves (SAW), colorimetric, chemoresistive, etc.
The current paper reports on a sonochemical synthesis method for manufacturing nanostructured (typical grain size of 50 nm) SrTi0.6Fe0.4O2.8 (Sono-STFO40) powder. This powder is characterized using X ray-diffraction (XRD), Mössbauer spectroscopy and Scanning Electron Microscopy (SEM), and results are compared with commercially available SrTi0.4Fe0.6O2.8 (STFO60) powder. In order to manufacture resistive oxygen sensors, both Sono-STFO40 and STFO60 are deposited, by dip-pen nanolithography (DPN) method, on an SOI (Silicon-on-Insulator) micro-hotplate, employing a tungsten heater embedded within a dielectric membrane. Oxygen detection tests are performed in both dry (RH = 0%) and humid (RH = 60%) nitrogen atmosphere, varying oxygen concentrations between 1% and 16% (v/v), at a constant heater temperature of 650 °C. The oxygen sensor, based on the Sono-STFO40 sensing layer, shows good sensitivity, low power consumption (80 mW), and short response time (25 s). These performance are comparable to those exhibited by state-of-the-art O2 sensors based on STFO60, thus proving Sono-STFO40 to be a material suitable for oxygen detection in harsh environments.
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