Higher house dust levels of PBDE flame retardants (FRs) have been
reported in California than other parts of the world, due to the state’s
furniture flammability standard. However, changing levels of these
and other FRs have not been evaluated following the 2004 U.S. phase-out
of PentaBDE and OctaBDE. We analyzed dust collected in 16 California
homes in 2006 and again in 2011 for 62 FRs and organohalogens, which
represents the broadest investigation of FRs in homes. Fifty-five
compounds were detected in at least one sample; 41 in at least 50%
of samples. Concentrations of chlorinated OPFRs, including two (TCEP
and TDCIPP) listed as carcinogens under California’s Proposition
65, were found up to 0.01% in dust, higher than previously reported
in the U.S. In 75% of the homes, we detected TDBPP, or brominated
“Tris,” which was banned in children’s sleepwear
because of carcinogenicity. To our knowledge, this is the first report
on TDBPP in house dust. Concentrations of Firemaster 550 components
(EH-TBB, BEH-TEBP, and TPHP) were higher in 2011 than 2006, consistent
with its use as a PentaBDE replacement. Results highlight the evolving
nature of FR exposures and suggest that manufacturers continue to
use hazardous chemicals and replace chemicals of concern with chemicals
with uncharacterized toxicity.
This study investigates the occurrence of 37 organohalogen and organophosphate flame retardants (FRs) from Norwegian households (n = 48) and classrooms from two primary schools (n = 6). Around 80% of the targeted FRs were detected in air and dust from the sampling sites. The comparison of settled dust with floor dust revealed no statistical differences between median concentrations of the FRs (n = 12). Decabromodiphenyl ether and tris(2-butoxyethyl) phosphate showed the highest median floor dust concentrations in both environments. In the air samples, the highest concentrations were observed for 2,2',4,4'-tetrabromodiphenyl ether and tris(1-chloro-2-propyl) phosphate. Remarkably, the emerging FR, 4-(1,2-dibromoethyl)-1,2-dibromocyclohexane, abbreviated as TBECH or DBE-DBCH, showed the highest indoor air concentrations reported in the literature (households, 77.9 pg/m(3) and schools, 46.6 pg/m(3)). Good Spearman correlations between the FR concentrations in dust and air (0.36 < R < 0.76) showed that is possible to estimate the concentrations in air from analyzed dust, or vice versa. Sources and pathways of exposure to FRs were assessed for the households. The main findings were that frequent vacuum cleaning resulted in lower FR concentrations in dust and that dermal contact with dust, for both children and mothers, was as important for the intake of organophosphate FRs as dust ingestion.
Polybrominated diphenyl ethers (PBDEs) have previously been detected in children toys, yet the risk of child exposure to these chemicals through the mouthing of toys or other items is still unknown. We aimed to expand on the current knowledge by investigating the impact of infants' mouthing activities on exposure to PBDEs present in toys. This was established by a leaching model for determining the amount PBDEs that can leach from toys into saliva in simulated conditions. The PBDE migration rate was at its highest for the 15 min low-exposure scenario incubations (198 pg/cm(2) × min) with the ERM EC-591 certified reference material (CRM) (0.17% w/w PBDEs). The leaching process was congener-dependent, since the percentage of lower brominated PBDE congeners that leached out was up to 4.5 times higher than for the heavier PBDEs. To study the scenario in which a child would mouth on a toy flame retarded with BDE 209 alone, a plastic item containing 7% BDE 209 (w/w) was also tested. The BDE 209 amounts leached out in only 15 min were higher than the amounts leached from the CRM after the 16 h incubation. For the Belgian population, the exposure scenario from mouthing on toys containing PBDEs in amounts similar to the REACH threshold was found to be lower than the exposure from mother's milk, but higher than the exposure through diet or even dust.
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