We propose a novel strategy to enhance optoelectrical properties of single-walled carbon nanotube (SWCNT) films for transparent electrode applications by film patterning. First, we theoretically considered the effect of the conducting pattern geometry on the film quality factor and, then, experimentally examined the calculated structures. We extend these results to show that the best characteristics of patterned SWCNT films can be achieved using the combination of initial film properties: low transmittance and high conductivity. The proposed strategy allows the patterned layers of SWCNTs to outperform the widely used indium-tin-oxide electrodes on both flexible and rigid substrates.Recent development of optoelectronic and photonic technologies for compact devices have introduced new challenges in fabrication of flexible, stretchable, transparent and conductive electrodes 1-3 . A wide range of possible applications includes solar cells 4 , light emitting diodes (LEDs) 5-7 , touchscreens 1,8,9 , "smart" devices, and wearable electronics 2,10 . The typical requirement for these applications is high transmittance in the middle of the visible spectral range and low sheet resistance. A few recent works have recently proposed new approaches, which allowed competing with highly efficient, indium-tin-oxide (ITO) coatings, one of the most developed and spread transparent conductive film (TCF) materials 1,11 . However, poor mechanical properties, high refractivity and price 2,12-14 , made researchers and engineers to search for alternative TCFs. Remarkable results were obtained with Cu and Ag nanofibers and nanowires 15 ,
Tailorable synthesis of axially heterostructured epitaxial nanowires (NWs) with a proper choice of materials allows for the fabrication of novel photonic devices, such as a nanoemitter in the resonant cavity. An example of the structure is a GaP nanowire with ternary GaPAs insertions in the form of nano-sized discs studied in this work. With the use of the micro-photoluminescence technique and numerical calculations, we experimentally and theoretically study photoluminescence emission in individual heterostructured NWs. Due to the high refractive index and near-zero absorption through the emission band, the photoluminescence signal tends to couple into the nanowire cavity acting as a Fabry–Perot resonator, while weak radiation propagating perpendicular to the nanowire axis is registered in the vicinity of each nano-sized disc. Thus, within the heterostructured nanowire, both amplitude and spectrally anisotropic photoluminescent signals can be achieved. Numerical modeling of the nanowire with insertions emitting in infrared demonstrates a decay in the emission directivity and simultaneous rise of the emitters coupling with an increase in the wavelength. The emergence of modulated and non-modulated radiation is discussed, and possible nanophotonic applications are considered.
We study the impact of improved heat removal on the performance of InGaAs/GaAs microdisk lasers epi-side down bonded onto a silicon substrate. Unlike the initial characteristics of microlasers on a GaAs substrate, the former’s bonding results in a decrease in thermal resistance by a factor of 2.3 (1.8) in microdisks with a diameter of 19 (31) µm, attributed to a thinner layered structure between the active region and the substrate and the better thermal conductivity of Si than GaAs. Bonded microdisk lasers show a 2.4–3.4-fold higher maximum output power, up to 21.7 mW, and an approximately 20% reduction in the threshold current. A record high 3 dB small-signal modulation bandwidth of 7.9 GHz for InGaAs/GaAs microdisk lasers is achieved.
Self-healing materials are an essential emerging class of smart materials, capable of repairing their damage after external stimuli, especially mechanical damages. However, the lack of studies on self-healing polymers after electrical breakdown is highly important for electrical engineering and electronics. We propose to use a nickel(II)-2,6-pyridinedicarboxamide-co-polydimethylsiloxane complex (NiPyPDMS) as an electrical breakdown protective material. To provide the absence of dust deposition from ambient air and to increase durability, we fabricated multilayered polymer “sandwiches” consisting of a NiPyPDMS layer covered with two films (polypropylene (PP) or polydimethylsiloxane (PDMS)) on both sides. Multilayered PP-NiPyPDMS-PP and PDMS-NiPyPDMS-PDMS films exhibit autonomous self-healing properties (up to 75%) after electrical breakdown at room temperature. NiPyPDMS demonstrates 3.7 times higher adhesion to copper, from which power lines are made, compared to PDMS. NiPyPDMS also exhibits antistatic and redox properties (NiII/NiIII transformations when electricity is applied). All characteristics mentioned above lead to reduce the probability of electrical breakdown via electrical charge dissipation in self-healing coating on possible power lines.
Semiconductor nanowires are the perfect platform for nanophotonic applications owing to their resonant, waveguiding optical properties and technological capabilities providing control over their crystalline and chemical composition. Vapor-liquid-solid growth mechanism...
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