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In frustrated spinel antiferromagnets, dilution with non-magnetic ions can be a powerful strategy for probing unconventional spin states or uncovering interesting phenomena. Here, we present X-ray, neutron scattering and thermodynamic studies of the effects of magnetic dilution of the tetragonally-distorted A-site spinel antiferromagnet, CuRh2O4, with non-magnetic Zn 2+ ions. Our data confirm the helical spin order recently identified at low-temperatures in this material, and further demonstrate a systematic suppression of the associated Néel temperature with increasing site dilution towards a continuous transition with critical doping of xspin ∼ 0.44. Interestingly, this critical doping is demonstrably distinct from a second structural critical point at xJT ∼ 0.6, which is consistent with the suppression of orbital order on the A-site through a classical percolative mechanism. This anomalously low value for xspin is confirmed via multiple measurements, and is inconsistent with predictions of classical percolation theory, suggesting that the spin transition in this material is driven by an enhancement of pre-existing spin fluctuations with weak dilution.

Significance The essential physics of the cuprate high-temperature superconductors have been a central focus of condensed-matter physics for more than three decades. Although initially controversial, it is now clear that a ubiquitous tendency toward charge-density-wave (CDW) order is intertwined with the superconductivity. However, this manifests differently in distinct cuprates. On the basis of extensive X-ray and neutron scattering studies of the temperature and doping dependence of the CDW and spin-density-wave (SDW) correlations in one representative cuprate and a comparison with existing studies on other cuprates, we show that there plausibly is a single, preferred CDW order at the microscale, whose manifestation at low temperatures is modified in predictable ways by material-specific details, including its interaction with SDW order.

The manipulation of mesoscale domain wall phenomena has emerged as a powerful strategy for designing ferroelectric responses in functional devices, but its full potential is not yet realized in the field of magnetism. This work shows a direct connection between magnetic response functions in mechanically strained samples of Mn 3 O 4 and MnV 2 O 4 and stripe-like patternings of the bulk magnetization which appear below known magnetostructural transitions. Building off previous magnetic force microscopy data, a small-angle neutron scattering is used to show that these patterns represent distinctive magnetic phenomena which extend throughout the bulk of two separate materials, and further are controllable via applied magnetic field and mechanical stress. These results are unambiguously connected to the anomalously large magnetoelastic and magnetodielectric response functions reported for these materials, by performing susceptibility measurements on the same crystals and directly correlating local and macroscopic data.

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