The mineralogy, petrography and major‐ and trace‐element composition of iron ores from Elba Island (Tuscany, Italy), one of the most important iron sources in the Mediterranean area since the first millennium bc, revealed that hematite‐rich ores display prominent enrichments in W and Sn (up to 4950 μg g−1 and 8400 μg g−1, respectively). These two elements are hosted by tiny grains of W–Sn mineral phases (ferberite, scheelite and cassiterite) that are disseminated throughout the hematite matrix. A comparison with iron ores from many Italian and European localities (most of which were exploited in ancient times) suggests the uniqueness of the geochemical pattern of Elba Island hematite‐rich ores (i.e., high W and Sn, low Mo and low Cu, Pb and Zn). We suggest that this geochemical signature may represent a new provenance marker not only for discarded ore at smelting/smithing sites, but, possibly, also for metallurgical slag and smelted metal produced in the chaîne opératoire of the iron process.
In various ancient authors (e.g. the ‘Argonautika’ of Apollonios Rhodios) curious news about the Island of Elba can be found, concerning the existence, somewhere on the shore near Portoferraio, of pebbles that are ‘dirty’ from the Argonauts' sweat. The Argonauts are said to have stopped on the island during their journey back from the looting of the ‘Golden Fleece’. These pebbles are found to be typical of the gravelly beaches below the Capo Bianco cliffs. Such walls are made up of a bony-white aplitic rock dotted with blue-black tourmaline spots. Capo Bianco aplite is the uncommon result of the solidification of a boron-rich magma in a subvolcanic setting. Here, the separation of a boron-rich fluid phase gave way to the crystallization of peculiar spherical dark tourmaline clots in a very fine-grained white groundmass. This rock was noted by Argonauts (i.e. the ancient travellers they represent) and used as a lighthouse to the harbour of Argoos limen (now Portoferraio). Also in the myth, the unique mottled pebbles were recorded as stained by the Argonauts' sweat. The occurrence, within the same, complex myth, of ‘data’ concerning navigation (the white cliffs) and geology (description of the spotted aplite) identify the Argonauts as a blending of mineral prospectors, explorers and early eighteenth century-like naturalists, legitimatizing the commercial/political presence of Greeks in the region.
Cereals were very important in ancient diets, however evidence from archaeological sites of the vessels used for processing or storing cereals is comparatively rare. Micro-organisms, as well as chemical-physical effects can easily degrade cereals during the burial period. This can lead to a complete cereal decay and to serious difficulties in estimating the intensity of use of the cereals by ancient populations. Here, we present a novel biomarker approach entailing the detection of secondary lipid metabolites produced by ergot fungi (genus Claviceps), which are common cereal pests. The aim was to identify the original presence of Gramineae and to indirectly establish if vessels were used for cereal storage/processing. The fatty acid and TAG-estolide profiles of the remains from more than 30 archaeological vessels were investigated by gas chromatography/mass spectrometry (GC/MS) and high performance liquid chromatography/high resolution mass spectrometry (HPLC/ESI-Q-ToF). The detection of lipids derived from ergot in archaeological and historic contexts rests on its complex chemistry, providing a unique and relatively recalcitrant chemical signature for cereals. This research demonstrated that the combination of our innovative biomarker approach along with environmental and archaeological evidence can provide unprecedented insights into the incidence of cereals and related processing activities in ancient societies.
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