Since late Miocene time, post-collisional extension of the internal parts of the Apennine orogenic belt has led to the opening of the Tyrrhenian basin. Extensive, mainly acidic peraluminous magmatism affected the Tuscan Archipelago and the Italian mainland during this time, building up the Tuscan Magmatic Province as the fold belt was progressively thinned, heated and intruded by mafic magmas. An intrusive complex was progressively built on western Elba Island by emplacement, within a stack of nappes, of multiple, shallow-level porphyritic laccoliths, a major pluton, and a final dyke swarm, all within the span from about 8 to 6.8 Ma. New geochemical and Sr–Nd isotopic investigations constrain the compositions of materials involved in the genesis of the magmas of Elba Island compared to the whole Tuscan Magmatic Province. Several distinct magma sources, in both the crust and mantle, have been identified as contributing to the Elba magmatism as it evolved from crust-, to hybrid-, to mantle-dominated. However, a restricted number of components, geochemically similar to mafic K-andesites of the Island of Capraia and crustal melts like the Cotoncello dyke at Elba, are sufficient to account for the generation by melt hybridization of the most voluminous magmas (c. εNd(t) −8.5, 87Sr/86Sr 0.715). Unusual magmas were emplaced at the beginning and end of the igneous activity, without contributing to the generation of these hybrid magmas. These are represented by early peraluminous melts of a different crustal origin (εNd(t) between −9.5 and −10.0, 87Sr/86Sr variable between 0.7115 and 0.7146), and late mantle-derived magma strongly enriched in incompatible elements (εNd(t) = −7.0, 87Sr/86Sr = 0.7114) with geochemical–isotopic characteristics intermediate between contemporaneous Capraia K-andesites and later lamproites from the Tuscan Magmatic Province. Magmas not involved in the generation of the main hybrid products are not volumetrically significant, but their occurrence emphasizes the highly variable nature of crust and mantle sources that can be activated in a short time span during post-collisional magmatism.

No abstract

The Istituto di Geoscienze e Georisorse (IGG), on behalf and with the support of the International Atomic Energy Agency (IAEA), prepared eight geological materials (three natural waters and five rocks and minerals), intended for a blind interlaboratory comparison of measurements of boron isotopic composition and concentration. The materials were distributed to twenty seven laboratories ‐ virtually all those performing geochemical boron isotope analyses in the world ‐which agreed to participate in the intercomparison exercise. Only fifteen laboratories, however, ultimately submitted the isotopic and/or concentration results they obtained on the intercomparison materials. The results demonstrate that interlaboratory reproducibility is not well reflected by the precision values reported by the individual laboratories and this observation holds true for both boron concentration and isotopic composition. The reasons for the discrepancies include fractionations due to the chemical matrix of materials, relative shift of the zero position on the δ11B scale and a lack of well characterized materials for calibrating absolute boron content measurements. The intercomparison materials are now available at the IAEA (solid materials) and IGG (waters) for future distribution.

No abstract

HAL is a multi-disciplinary open access archive for the deposit and dissemination of scientific research documents, whether they are published or not. The documents may come from teaching and research institutions in France or abroad, or from public or private research centers. L'archive ouverte pluridisciplinaire HAL, est destinée au dépôt et à la diffusion de documents scientifiques de niveau recherche, publiés ou non, émanant des établissements d'enseignement et de recherche français ou étrangers, des laboratoires publics ou privés.

In 1999 the Istituto di Geoscienze e Georisorse (IGG), with the support of the International Atomic Energy Agency (IAEA), undertook the collection, preparation and distribution of eight geological materials intended for a blind interlaboratory comparison of measurements of boron isotopic composition and concentration. The materials came from Italian sources and consist of three natural waters (Mediterranean seawater and two groundwaters) and five rocks and minerals (tourmaline, basalt, obsidian, limestone and clay). The solid materials were crushed, milled and mixed, in preparation for distribution. Extensive assays performed at the IGG on these materials demonstrated that their boron isotopic and chemical compositions are homogeneous. Additional homogeneity tests were carried out on solid material fragments at the GeoForschungsZentrum Potsdam, with the specific objective of investigating the suitability of some of them for the calibration in situ of micro‐analytical techniques. Two materials, B4 (tourmaline) and B6 (obsidian), proved to be isotopically homogeneous and may become excellent references for in situ microanalyses of boron isotopes. The materials described here were used as the basis of a major laboratory intercomparison study and are now available for further distribution from either the IAEA (solid materials) or the IGG (waters).

The Betic‐Rif orogen forms the western termination of the Alpine orogenic system in the Mediterranean region. The precise timing, structural evolution, and distribution of high‐grade metamorphic units (Alpine versus pre‐Alpine) in the inner zones of the orogen (Alboran Domain) remain controversial issues. In this paper we report occurrence of distinct generations of peraluminous granitic bodies intruded within Beni Bousera peridotites and their amphibolite‐to‐granulite facies envelope, in the core of the Alboran Domain of the Rif chain (northern Morocco). These granitic bodies are central to the reconstruction of the high‐grade evolution of the Alboran Domain because they provide first‐order structural markers to assess the P‐T‐t deformation history of the high‐grade terranes. Here we document the petrography and structural relationships with the host rocks and constrain the timing of granite emplacement using laser ablation–inductively coupled plasma–mass spectrometry U‐Pb zircon and/or monazite dating, complemented by 40Ar/39Ar dating. The results indicate that granite emplacement occurred in two major episodes of anatectic magmatism, during the Hercynian (circa 300 Ma) and Alpine (circa 22 Ma) periods, respectively. These data (1) provide conclusive evidence for an important phase of Hercynian magmatism and high‐grade metamorphism in the Alboran Domain and (2) permit a revaluation of the significance of the high‐grade early Miocene event documented in the Alboran Domain in terms of a late stage, thermal pulse that reworked a polymetamorphic (Hercynian and Alpine) nappe pile. These results provide new constraints for construction of a feasible tectonometamorphic model for the Alpine evolution of the western Mediterranean.

In two separate areas of western and central Elba Island (Italy), Late Miocene granite porphyries are found as shallow-level intrusions inside a stack of nappes rich in physical discontinuities. Detailed mapping of intrusive rocks, along with their relations with country rocks, show that outcrops from western and central Elba Island expose the same rock types, with matching intrusive sequence, petrography and geochemical features. Structural and geological data indicate that these layers were originally part of a single sequence that was split by eastward-directed d6collement and tilting. The two juxtaposed portions of the original sequence allow the restoration of a 5-km thick sequence, made up of nine main intrusive layers, building three Christmas-tree laccoliths nested into each other to support a structural dome. During their construction, the role of the neutral buoyancy level was of minor significance with respect to the role played by the relatively thin overburden and/or the large availability of magma traps inside the intruded crustal section. Emplacement of the Monte Capanne pluton into the base of the domal structure likely caused oversteepening and initiated decapitation of the complex, with gravity sliding of the upper half off the top.