Crystallite size is one of the fundamental factors controlling the magnetic property of magnetic nanoparticles. In this study, magnetite nanoparticles were produced from Ethiopian iron ore and the effect of solvent extraction parameters on the crystallite size were investigated by considering classical nucleation theory. First, the iron ore was crushed and unwanted gangues were discarded, then followed by further grinding to get a black powder. Finally, the magnetite nanoparticles were produced using solvent extraction and co-precipitation method. For the solvent extraction, tri-butyl phosphate (TBP) and tri-octyl phosphine oxide (TOPO) was used as an extractant, while 2-ethyl-hexanol, and heptanol were used as a modifier and diluent, respectively. The synthesized nanoparticles was characterized using XRD, SEM (EDS), TGA, and FTIR. The results show that leaching temperature and modifier concentration have a significant effect on the crystallite size of the nanoparticles. Comparison of the crystallite size using the Scherrer equation reveals the mean crystallite size of the sample extracted using TBP is smaller than the sample extracted using TOPO.
The research shows the characterization of mechanical properties in dissimilar steel welded unions: a structural steel ASTM A537 (I) overlap welded with an austenitic stainless steel ASTM A240 (304L) through semiautomatic electrical arc welding process protected by inert gas (GMAW); Argon is used as a protecting gas and austenitic stainless steel ASTM A240 (308L) as a supplier material. Samples were tested in not welded conditions so as to characterize the materials involved in the research, and they were also tested in welded conditions, not being submitted to pre and post welding Thermal Treatment (TT). Welded-based material samples were characterized through Optical Microscopy (OM) and Scanning Electron Microscopy (SEM), an inspection of Not Destructive Test (NDT) with penetrating liquids and ultrasound was also conducted. The following mechanical tests were completed, not only on the Base Metals (BM), on the Welding Join (WJ) as well: Vickers micro hardness profile, tension, and face bending test. Results showed a proper mechanical steel behavior, welded by GMAW procedure, under monotonic, in spite of the relatively high values of microhardness in the Heat Affected Zone (HAZ), specifically near the fusion line between weld and stainless steel.
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