10À30 esu, using the T convention) and high decomposition temperature (T d ¼ 312 C), thus indicating its potential application as a useful material for incorporation into non-linear optical devices.
Precursors to three new 3,4-ethylenedioxythiophene (EDOT) incorportaing dyes have been synthesisedviaa one-pot C–H activation route usingN,N-dimethylaniline as a donor group.
Chemical redox reactions have been exploited to transform unreactive vinylferrocene into a powerful dienophile for the Diels-Alder reaction and reactive substrate for thiol addition reactions upon conversion to its ferrocenium state. We have further investigated the ability of these reactions to facilitate redox-auxiliary-like reactivity by further hydrogenolyisis of the Diels-Alder adduct to the corresponding cyclopentane derivative.
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