A significant increase in electroluminescence was achieved through coupling with localized surface plasmons in a single layer of Au nanoparticles. We fabricated a thin-film organic electroluminescence diode, which consists of an indium tin oxide (ITO) anode, a Au nanoparticle array, a Cu phthalocyanine hole transport layer, a tris(8-hydroxylquinolianato) aluminum (III) electron transport layer, a LiF electron injection layer, and an Al cathode. The device structure, with size-controlled Au particles embedded on ITO, can be used to realize the optimum distance for exciton-plasmon interactions by simply adjusting the thickness of the hole transport layer. We observed a 20-fold increase in the molecular fluorescence compared with that of a conventional diode structure.
A molecular wire candidate, the polydiacetylene chain, fabricated in a substantial support layer of monomers self-assembled on a highly ordered pyrolytic graphite surface, was studied using scanning tunneling microscopy and spectroscopy. The density of states of individual polymers and constituent monomers were observed on the same surface, and then compared with the calculated results. The spectrum delineating the density of states of the polydiacetylene wire clearly reveals the theoretically predicted pi-band and band edge singularities of the one-dimensional polymer.
The main components of a new beamline for surface and interface crystal structure determination at SPring-8 are briefly described. Stages for the beamline monochromator are modified for making an incident X-ray intensity more stable for surface X-ray experiments. Absolute photon flux densities were measured with an incident photon energy. A new ultrahigh vacuum system is introduced with preliminary X-ray measurements from an ordered oxygen on Pt (111) surface.
The blue coloration of Morpho butterflies has anomalously low angular dependence despite the production of color with a selected wavelength based on an interference effect. A key to the mechanism of the specific Morpho-color was suggested to be the randomness of its scale. Using finite-difference time-domain (FDTD) analysis, the role of different kinds of randomness in the structure of the Morpho butterfly's scale was investigated, which was impossible by conventional analytical calculations. The results revealed that incoherence in the incident light plays an essential role, which cannot be realized only by structural randomness. On the other hand, the lateral and vertical randomness, and the number of random components were found each to have an independent role to realize the specific Morpho-color preventing the sharp reflective angular dependence. The direction obtained by the numerical simulations to analyze optically complex random structures will serve not only to understand the scientific principles, but also to design the optical properties of artificial materials.
Relative angle determinable stitching interferometry for hard x-ray reflective optics Rev. Sci. Instrum. 76, 045102 (2005); 10.1063/1.1868472 X-ray wavefront analysis and optics characterization with a grating interferometer A new stitching interferometry based on a microscopic interferometer having peak-to-valley height accuracy of subnanometer order and lateral resolution higher than 20 m was developed to measure surface figures of large-size x-ray mirror optics. Cumulative errors of the stitching angle in a long spatial wavelength range were effectively reduced to be 1ϫ10 Ϫ7 rad levels using another interferometer having a large cross section in the optical cavity. Some optical performances of ultraprecise x-ray mirrors, such as submicrofocused beam profile, were wave optically calculated from the measured surface figure profiles and observed at the 1 km long beamline ͑BL29XUL͒ of SPring-8. Observed and wave optically calculated results were in good agreement with a high degree of accuracy.
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