The prepared amine-impregnated cellulose (AIC) was found to be an efficient adsorbent for uranium originated from El-Sebaiya phosphate ore. The impregenation process was carried out by copolymerization between pretreated cellulose and a mixture of (tri-ethyl amine and epi-chorohydrine).In the present work, two working solutions were used. The first solution was a synthesized phosphoric acid (35% P 2 O 5 and 100 ppm U) used for optimizing the loading process of uranium. The second one was used as a case study for adsorption of uranium from a real phosphoric acid (WPPA) prepared from El-Sebaiya phosphate ore (P 2 O 5 35%, 100 ppm U).The obtained equilibrium data were found to be satisfactory fitted with Langmuir isotherm.A maximum-metal uptake of 56.5 mgU/g AIC was observed at the obtained optimum conditions. Also, elution process of uranium has been achieved at 1 M of 30 ml Na 2 CO 3 solution/g AIC after 15 min contact time. From the latter, a marketable product of sodium di-uranate was prepared.
To avert excessive sulfuric acid exhaustion in the classical leaching procedure and to avoid leaching of other undesirable impurities, proper alkaline leaching has been achieved for dolostone of Gabal Allouga, Southwestern Sinai, Egypt. The relevant factors for alkaline leaching of a technological sample assaying 1.2% Cu and 0.15% U were examined using a mixture of Na 2 CO 3 / (NH 4) HCO 3 solution upon two samples namely; roasted sample at 540°C and raw materials un-roasted. The leaching kinetic results showed that the leaching procedure of uranium and copper from dolostone is controlled by shrinking core kinetic model 1-2/3(X)−(1−X) 2/3 = k d t.
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