Environment friendly, flexible, and robust sensors have attracted considerable research attention due to their potential for a wide range of devices in energy generation and harvesting, sensing, and biomedical applications. In this manuscript, we demonstrate a lead-free, solution processed flexible piezoelectric energy generator based on a nanocomposite film, consisting of MgO nanoparticles of sizes around <50 nm, embedded in poly(vinylidene difluoride) [PVDF] and its copolymer with trifluoroethylene, that is, P(VDF-TrFE) matrix. Piezoelectric, ferroelectric, and leakage current measurements made on samples with various concentrations of MgO nanoparticles revealed a dramatic improvement in these characteristics at 2 wt % MgO with nearly 50% increase in the piezoelectric coefficient as compared to pure P(VDF-TrFE), attributed to the preferred conformation of P(VDF-TrFE) chain, improved crystallinity of the P(VDF-TrFE) matrix, and uniform distribution of nanoparticles. Assessment of the interactions between -OH groups attached to MgO surface and P(VDF-TrFE), carried out using Fourier-transform infrared spectroscopy (FTIR), suggested weak van der Waals forces between -OH groups and P(VDF-TrFE) being responsible for the observed improvement. This flexible nanocomposite device exhibits superior energy harvesting performance with over two-times improvement in the voltage output (2 V) compared to device using P(VDF-TrFE) films alone. Along with superior electrical properties, nanocomposites also exhibit excellent endurance against electrical as well as mechanical fatigue, with piezoelectric coefficient remaining unchanged even after 10 000 bending cycles, supporting their suitability in flexible energy harvesting applications.
Solid polymer electrolytes (SPEs) provide a potential to enable lithium-ion and lithium-metal batteries to achieve high energy density, advanced manufacturing capabilities, and enhanced safety. However, the currently available SPEs do not yield the desired Li + conductivity at ambient temperatures. The design strategies for polymer electrolytes often rely on the expectation of dynamical decoupling between ionic conductivity and polymer segmental relaxation, yet the underlying physics of assumed "decoupling" is unclear. In this Letter, atomistic molecular dynamics simulations are used to investigate the molecular origin of coupling− decoupling phenomena between Li + mobility and polymer dynamics for a series of polymer architectures resulting in similar Li + coordination environments. A transition from strong coupling between Li + and the polymer segmental motion regime to a decoupling regime is clearly observed. In the latter regime, while anion motion shows a strong correlation with polymer segmental dynamics, the Li + transport remains almost constant in systems where the polymer dynamics differs by orders of magnitude.
Solid polymer electrolytes (SPEs) have attracted considerable attention for high energy solid-state lithium metal batteries (LMBs). In this work, potentially ecofriendly, solid-state poly(𝝐-caprolactone) (PCL)-based star polymer electrolytes with cross-linked structures (xBt-PCL) are introduced that robustly cycle against LiNi 0.6 Mn 0.2 Co 0.2 O 2 (NMC622) composite cathodes, affording long-term stability even at higher current densities. Their superior features allow for sufficient suppression of dendritic lithium deposits, as monitored by 7 Li solid-state NMR. Advantageous electrolyte|electrode interfacial properties derived from cathode impregnation with 1.5 wt% PCL enable decent cell performance until up to 500 cycles at rates of 1C (60 °C), illustrating the high potential of PCL-based SPEs for application in high-voltage LMBs.
IntroductionAs essential component within lithium-based batteries, the electrolyte plays a vital role for achieving long-term electrochemical performance and safety. Despite their potential in providing high specific capacity, current lithium metal batteries (LMBs) are eventually limited by inhomogeneous lithium deposition (high-surface area lithium (HSAL)) or disadvantageous
Contamination of natural water resources
by per- and polyfluorinated
alkyl substances (PFAS) has affected millions of people around the
world and emphasized the need for development of novel and effective
adsorbent materials. We demonstrate how atomistic molecular dynamics
(MD) simulations can be used to provide molecular scale insight into
the role of electrostatic and hydrophobic interactions on the adsorption
of the perfluorooctanoate (PFOA) surfactant, a prominent longer-chain
PFAS, on a polymer-based network in water. Specifically, the adsorption
of ammonium perfluorooctanoate salt has been investigated on the β-cyclodextrin
(CD) network cross-linked with decafluorobiphenyl linkers as an example
of an absorbent material that has already demonstrated efficient PFAS
adsorption. Examination of pairwise interactions reveals the importance
of the dual pronged adsorption mechanism involving both electrostatic
and hydrophobic interactions. The adsorption of ammonium counterions
on the CD segments facilitates attraction of the anionic headgroup
of the PFOA surfactant, while fluorinated linkers provide an additional
hydrophobic attraction for the PFOA tail as well as higher affinity
of the network toward PFOA in comparison with hydrocarbons. These
competing interactions result in PFOA adsorption primarily outside
of the CD cavity with the PFOA tail mostly interacting with fluorinated
linkers. We demonstrate that simulations using “what if”
scenarios are a powerful approach to infer the role of different interactions
in the adsorption of PFAS.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.