Waste tire disposal continues to pose a threat to the environment due to its non-biodegradable nature. Therefore, some means of managing waste tires include grinding them to crumb rubber (CR) sizes and using them as a partial replacement to fine aggregate in concrete. However, the use of CR has a series of advantages, but its major disadvantage is strength reduction. This leads to the utilization of calcium carbide waste (CCW) to mitigate the negative effect of CR in self-compacting concrete (SCC). This study investigates the durability properties of SCC containing CR modified using fly ash and CCW. The durability properties considered are water absorption, acid attack, salt resistance, and elevated temperature of the mixes. The experiment was conducted for mixes with no-fly ash content and their replica mixes containing fly ash to replace 40% of the cement. In the mixes, CR was used to partially replace fine aggregate in proportions of 0%, 10%, and 20% by volume, and CCW was used as a partial replacement to cement at 0%, 5%, and 10% by volume. The results indicate that the mixes containing fly ash had higher resistance to acid (H2SO4) and salt (MgSO4), with up to 23% resistance observed when compared to the mix containing no fly ash. In addition, resistance to acid attack decreased with the increase in the replacement of fine aggregate with CR. The same principle applied to the salt attack scenario, although the rate was more rapid with the acid than the salt. The results obtained from heating indicate that the weight loss was reduced slightly with the increase in CCW, and was increased with the increase in CR and temperature. Similarly, the compressive strength was observed to slightly increase at room temperature (27 °C) and the greatest loss in compressive strength was observed between the temperature of 300 and 400 °C. However, highest water absorption, of 2.83%, was observed in the mix containing 20% CR, and 0% CCW, while the lowest water absorption, of 1.68%, was found in the mix with 0% CR, 40% fly ash, and 10% CCW. In conclusion, fly ash is recommended for concrete structures immersed in water, acid, or salt in sulphate- and magnesium-prone areas; conversely, fly ash and CR reduce the resistance of SCC to heat beyond 200 °C.
The target of this study is to develop a spreading rate regression model capable of predicting rate of spread of Nigerian crude oil spills on water. The major factors responsible for spreading rate of crude oil on water were considered, namely surface tension, viscosity, and specific gravity/American Petroleum Institute degree (0 API), all at specified temperature values. The surface tension, viscosity and density parameters were interactively measured under controlled factorial analysis. The spreading rate of each crude oil was determined by artificially spilling them on laboratory calm/stagnant water in a rectangular tank and their averages were also computed. These averages were used to develop a regression model equation for spreading rate. The model developed indicated that an average spreading rate was 3.3528 cm/s at 37.5˚C and the predictive regression model is evaluated with the interactions of specific gravity, viscosity and surface tension. It is convenient to state that the model will predict the spread rate of crude oils which possess imputed physicochemical properties having pour point averaged 15.5˚C on calm seawater.
Global warming and climate changes are the major environmental challenges globally. With CO2 emission being one of the main greenhouse gases emitted to the environment, and cement and concrete production amounting to about 10% of the global CO2 emission, there is a need for the construction industry to utilize an environmentally sustainable material as an alternative to cement. This study analyzed the cost, CO2 emission and strength properties of green self-compacting concrete (SCC) ternary blend containing fly ash, calcium carbide residue (CCR), and crumb rubber (CR) as a replacement material by volume of cement, cementitious material, and fine aggregate, respectively. Cement was replaced with fly ash at 0 and 40% by volume. CCR was used as a replacement at 5 and 10% by volume of cementitious materials, CR replaced fine aggregate in proportions of 10 and 20% by volume. The result indicated that the mix with 0% fly ash and 20% CR replacement of fine aggregate was the most expensive and had the highest CO2 emission. However, the mix with 10% CR, 40% fly ash, and 10% CCR had the lowest CO2 emission and was therefore the greenest SCC mix. The 28-day maximum compressive strength of 45 MPa was achieved in a mix with 0% CR, 0% fly ash, and 10% CCR, while the utmost 28-day splitting tensile strength of 4.1 MPa was achieved with a mix with 10% CR, 0% fly ash, and 5% CCR, and the highest flexural strength at 28 days was 6.7 MPa and was also obtained in a mix with 0% CR, 0% fly ash, and 5% CCR. In conclusion, a green SCC can be produced by substituting 40% cement with fly ash, 10% fine aggregate with CR, and 10% CCR as a replacement by volume of cementitious material, which is highly affordable and has an acceptable strength as recommended for conventional SCC.
Durability is one of the major concerns in concrete industries. Several attempts have been made to investigate the suitability of various supplementary materials from agricultural waste to increase the durability properties such as acid resistance, sulfate attack, alkaline attack, sorptivity, chloride permeability, elevated temperature, and water absorption self-compacting concrete mixes. However, this paper studied the durability properties of self-compacting concrete modified with millet husk ash (MHA) subjected to different environmental conditions such as sulfate attack from sulphuric acid and magnesium sulfate salt, elevated temperature, and water absorption. Grade 40 (control) SCC obtained from serries of trial mixes using 0.35 water-cement ratio was used for this study. Other mixes were derived from the control mix by replacing cement with 5, 10, 15, 20, 25, and 30 % by weight of MHA, respectively. The effects of sulfate elevated temperature and water absorption was evaluated for all mixes. The experimental results of this work showed that the MHA is a pozzolanic material and can reduce the ingress of water and sulfate attack on concrete. However, the addition of MHA reduces the heat-resisting capacity of concrete.
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