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In this work, multiwall carbon nanotubes (MWCNTs) developed from cobalt-ferrite catalyst on activated carbon (from castor seed), was used as an adsorbent for the removal of cadmium and hexavalent chromium ions. The effectiveness of the adsorbent for the uptake of Cd(II) and Cr(VI)ions from aqueous solution was investigated in a process batch adsorption study. The developed activated carbon and MWCNTs were characterized by Brunauer-Emmett-Teller (BET) surface area analysis, Fourier Infrared Spectroscopy (FT-IR) and Scanning Electron Microscopy (SEM) for the determination of surface area, functional group, and surface morphology, respectively. The BET surface area of activated carbon and developed adsorbent from Co-Fe/AC was 230.24 and 372.42 m 2 /g, respectively. The operational parameters evaluated on the adsorption efficiency were solution pH, temperature, adsorbent dosage initial metal ions concentration, and contact time. The adsorption of Cd(II) and Cr(VI) were found to have attained equilibrium positions in 60 min for the concentration range tested, respectively. The four linearized adsorption isotherm models; Langmuir, Freundlich, Temkin and Dubinin Radushkevich (D-R) tested, when compared, revealed that Langmuir isotherm fitted well to the experimental data judging from the higher correlation coefficient values (R 2 ) and lower values of the error functions (chi-square (χ 2 ), the sum of square error (ERRSQ/SSE) and the sum of absolute error (EABS))with monolayer adsorption capacities of 404.858 and 243.902 mg/g for Cd(II) and Cr(VI) ions, respectively. Adsorption kinetic models investigated by pseudo-first-order, pseudo-second-order, Elovich, and intraparticle diffusion showed the conformity of pseudo-second-order model to the process adsorption as informed by the higher values R 2 and Adj, R 2 , maximum log-likelihood and smaller ERRSQ/SSE, χ 2 , Akaike information criterion (AIC), Bayesian information criterion (BIC), and Hannan-Quinn information criterion (HQIC). The intraparticle diffusion model plots indicated that intraparticle diffusion was not the only rate-limiting step. Thermodynamic adsorption parameters (ΔH o and ΔG o , ΔS o ) showed that the adsorption of Cd (II) and Cr (VI) ions was spontaneous, endothermic, and increased in randomness between the adsorbate-adsorbent. The mean adsorption energy (E), the heat of adsorption (ΔH o ), and activation energy (E a ) values, revealed the adsorption mechanism of Cd(II) and Cr(VI) onto MWCNTs as a combination of chemical and physical adsorption but dominated more by chemical adsorption. IntroductionWater is particularly important to the existence of living organisms in the world. However, human activities which include population growth, industrialization increase, and urbanization have caused rapid contamination, compromising the availability of potable water [1]. The release of harmful substances like heavy metals, due to human actions, has posed environmental problems, affecting human health [2,3]. Heavy metals like chromium and cadmium when exceed...

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The target of this study is to develop a spreading rate regression model capable of predicting rate of spread of Nigerian crude oil spills on water. The major factors responsible for spreading rate of crude oil on water were considered, namely surface tension, viscosity, and specific gravity/American Petroleum Institute degree (0 API), all at specified temperature values. The surface tension, viscosity and density parameters were interactively measured under controlled factorial analysis. The spreading rate of each crude oil was determined by artificially spilling them on laboratory calm/stagnant water in a rectangular tank and their averages were also computed. These averages were used to develop a regression model equation for spreading rate. The model developed indicated that an average spreading rate was 3.3528 cm/s at 37.5˚C and the predictive regression model is evaluated with the interactions of specific gravity, viscosity and surface tension. It is convenient to state that the model will predict the spread rate of crude oils which possess imputed physicochemical properties having pour point averaged 15.5˚C on calm seawater.