No abstract

No abstract

No abstract

This paper describes the synthesis and characterization of a composite constituted by an antiarthritic agent (AA) intercalated into a layered double hydroxide (LDH) supported on magnesium ferrite. Core-shell nanocomposites were prepared by depositing Mg-Al-NO(3)-LDH on a MgFe(2)O(4) core prepared by calcination of a nonstoichiometric Mg-Fe-CO(3)-LDH. Intercalation of ibuprofen and glucuronate anions was performed by ion-exchange with nitrate ions. The structural characteristics of the obtained products were investigated by powder X-ray diffraction, element chemical analysis, Fourier transform infrared spectroscopy, and thermogravimetric analysis. Morphologies of the nanocomposite particles were examined by scanning electron microscopy and transmission electron microscopy. The products were shown to intercalate substantial amounts of AA with enhanced thermal stabilities. Room-temperature magnetic measurements by vibrating sample magnetometry revealed that the products show soft ferromagnetic properties suitable for potential utilization in magnetic arthritis therapy.

No abstract

The stratigraphy and age of the Neogene Cappadocia ignimbrites (Central Turkey) have been inferred in previous studies from fieldwork and K–Ar age determinations. The resulting stratigraphic schemes, however, differed from each other, suggesting that further studies were required to produce a reliable succession. In this paper, we examine the chronostratigraphy of mammalian remains recovered in the continental sediments interbedded with the Cappadocia ignimbrites. Using recent advances in mammalian chronostratigraphy, we evaluate selected taxa and faunal associations to place new and independent constraints on the ignimbrite ages. The biostratigraphically bracketed ages concur with some published radiometric dates, but they disagree with others, principally at localities where major stratigraphic discrepancies have arisen in the literature. In order to reconcile these apparent inconsistencies, we combine, at selected sites, our field observations with the biostratigraphic and radiometric age limits, and we compare these with the available geochemical and magnetic data. This allows us to present revised age estimates, and a revised stratigraphy which includes the correlation of the local Sofular deposits with the large-volume Gördeles ignimbrite. The issues faced in this study apply to other ignimbrite provinces in the world. For instance, ignimbrite eruption frequency in Cappadocia is higher than the resolution of many published K–Ar ages. Furthermore, different K–Ar ages have led to the description of individual and distinct ignimbrites that fieldwork and geochemical data allow to merge into a single ignimbrite. Argon loss from pumice samples leading to radiometric “rejuvenation” provides a likely explanation for most stratigraphic discrepancies. Cappadocia is the only documented ignimbrite field in which the chronostratigraphy of vertebrate remains provides better constraints on some ignimbrite ages than scattered K–Ar dates. We further argue that K–Ar dates from the Cappadocia area are too imprecise to establish a reliable magnetostratigraphic scheme for the ignimbrite succession, with the exception of the not, vert, similar2.8 Ma Valibaba Tepe ignimbrite

No abstract

Extensive continental collision-related volcanism occurred in Turkey during Neogene–Quaternary times. In central Anatolia, calc-alkaline to alkaline volcanism began in the Middle–Late Miocene. Here we report trace elemental and isotopic data from Quaternary age samples from central and eastern Anatolia. Most mafic lavas from central Anatolia are basalt and basaltic andesite, with lesser amounts of basaltic trachyandesite and andesite. All magma types exhibit enrichment in LILE (Sr, Rb, Ba and Pb) relative to HFSE (Nb, Ta). Trace element patterns are characteristic of continental margin volcanism with high Ba/Nb and Th/Nb ratios. 87Sr/86Sr and 143Nd/144Nd isotopic ratios of central Anatolian lavas range between 0.704105–0.705619 and 0.512604–0.512849, respectively. The Quaternary alkaline volcanism of eastern Anatolia has been closely linked to the collision between the Arabian and Eurasian plates. Karacadaǧ and Tendürek volcanic rocks are represented by alkali basalts and basaltic trachyandesites, respectively. As expected from their alkaline nature, they contain high abundances of LIL elements, but Tendürek lavas also show depletion in Nb and Ta, indicating the role of crustal contamination in the evolution of these magmas. 87Sr/86Sr and 143Nd/144Nd ratios of the Karacadaǧ and Tendürek lavas range from 0.703512 to 0.704466; 0.512742 to 0.512883 and 0.705743 to 0.705889 and 0.512676, respectively. Petrogenetic modelling has been used to constrain source characteristics for the central and eastern Anatolian volcanic rocks. Trace element ratio plots and REE modelling indicate that the central Anatolian volcanism was generated from a lithospheric mantle source that recorded the previous subduction events between Afro-Arabian and Eurasian plates during Eocene to Miocene times. In contrast, The Karacadaǧ alkaline basaltic volcanism on the Arabian foreland is derived from an OIB-like mantle source with limited crustal contamination. Tendürek volcanism, located on thickened crust, north of the Bitlis thrust zone, derived from the lithospheric mantle via small degrees (1.5 %) of partial melting.