Thermal transport in nanostructures has attracted considerable attention in the last decade but the precise effects of surfaces on heat conduction have remained unclear due to a limited accuracy in the treatment of phonon surface scattering phenomena. Here, we investigate the impact of phonon-surface scattering on the distribution of thermal energy across phonon wavelengths and mean free paths in Si and SiGe nanowires. We present a rigorous and accurate description of phonon scattering at surfaces and predict and analyse nanowire heat spectra for different diameters and surface conditions. We show that the decrease in the diameter and increased roughness and correlation lengths makes the heat phonon spectra significantly shift towards short wavelengths and mean free paths. We also investigate the emergence of phonon confinement effects for small diameter nanowires and different surface scattering properties. Computed results for bulk materials show excellent agreement with recent experimentally-based approaches that reconstruct the mean-free-path heat spectra. Our phonon surface scattering model allows for an accurate theoretical extraction of heat spectra in nanowires and contributes to elucidate the development of critical phonon transport modes such as phonon confinement and coherent interference effects.
Phonon-surface scattering is the fundamental mechanism behind thermal transport phenomena at the nanoscale. Despite its significance, typical approaches to describe the interaction of phonons with surfaces do not consider all relevant physical quantities involved in the phonon-surface interaction, namely, phonon momentum, incident angle, surface roughness, and correlation length. Here, we predict thermal conduction properties of thin films by considering an accurate description of phonon-surface scattering effects based on the rigorous Beckmann-Kirchhoff scattering theory extended with surface shadowing. We utilize a Boltzmann transport based reduced mean-free-path model for phonon transport in thin-films to predict the wavelength and mean-free-path heat spectra in Si and SiGe films for different surface conditions and show how the thermal energy distribution can be tailored by the surface properties. Using the predicted wavelength spectra, we also introduce a measure to quantify phonon-confinement effects and show an enhanced confinement in Ge alloyed Si thin films. The impact of surface roughness and correlation lengths on thermal conductivities is also studied, and our numerical predictions show excellent agreement with experimental measurements. The results allow to elucidate and quantitatively predict the amount of thermal energy carried by different phonons at the nanoscale, which can be used to design improved optoelectronic and thermoelectric devices.
Selective heating of different phases of multiphase systems via microwaves can result in energy savings and suppression of side reactions. However, materials properties and operating conditions that maximize temperature gradients are poorly understood. Here we utilize computational fluid dynamics (CFD) computations and temperature measurements in structured flow reactors (monoliths) in a monomodal microwave cavity to assess the temperature difference between the walls and the fluid and develop a simple lumped model to estimate when temperature gradients exist. We also explore the material's thermal and electrical properties of structured reactors for isothermal catalyst conditions. We propose that CFD simulations can be used as a nonintrusive, predictive tool of temperature homogeneity. Importantly, we demonstrate that localized heating in the bed under several conditions rather than selective heating is responsible for the selectivity enhancement. Our results indicate that structured beds made of high thermal conductivity materials avoid arcing and enable temperature homogeneity and low electrical conductivity materials allow microwaves to penetrate the domain.
Thermal conduction in semiconductor nanowires is controlled by the transport of atomic vibrations also known as thermal phonons. The ability of nanowires to tailor the transport of thermal phonons stems from their precise atomic scale growth coupled with high structural surface to volume ratios. Understanding and manipulating thermal transport properties at the nanoscale is central for progress in the fields of microelectronics, optoelectronics, and thermoelectrics. Here, we review state-of-the-art advances in the understanding of nanowire thermal phonon transport and the design and fabrication of nanowires with tailored thermal conduction properties. We first introduce the basic physical mechanisms of thermal conduction at the nanoscale and detail recent developments in employing nanowires as thermal materials. We discuss and provide insight on different strategies to modulate nanowire thermal properties leveraging the underlying phonon transport processes occurring in nanowires. We also highlight challenges and key areas of interest to motivate future research and create exceptional capabilities to control heat flow in nanowires.
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