In this study, effect of cell compression on the performance of a non-hot press membrane electrode assembly (MEA) for a polymer electrolyte membrane fuel cell (PEMFC) is presented. The MEA is made without hot pressing, by carefully placing the gas diffusion electrodes (GDEs) and a membrane in a fuel cell fixture. Cell performance is assessed at five different compression ratios between 3.6% and 47.8%. It has been shown that ohmic resistance of the cell, mass transport resistance of reactants, charge transfer resistance at electrode and overall cell performance are strongly dependent on the cell compression. On increasing the cell compression gradually, cell performance improves initially, reaches the best and then deteriorates. The cell performance is assessed at fully humidified condition and at dry condition. Optimum cell performances are obtained at compression ratios of 14.2% and 25.7% for 100% relative humidity (RH) and 50% RH, respectively. It is also found that the cell with proper compression and at fully humidified conditions can deliver similar performance to a conventional hot-pressed MEA. Finally, it is shown that after the tests, GDEs can be peeled out and the membrane inspection can be done as a post experimental analysis.
Highlights Novel, bio-inspired resilient resource and infrastructure network design framework. Proposed framework only requires knowledge of network architecture. Valuable tool when information not available for high-fidelity analyses. Shown to be able to analyze complex resource and infrastructure networks. Validated network resilience improvement through supply chain case-study.
The objective of this study is to investigate the value of an ecologically inspired architectural metric called the Degree of System Order in the System of Systems (SoS) architecting process. Two highly desirable SoS attributes are the ability to withstand and recover from disruptions (resilience) and affordability. In practice, more resilient SoS architectures are less affordable and it is essential to balance the trade-offs between the two attributes. Ecological research analyzing long-surviving ecosystems (nature's resilient SoS) using the Degree of System Order metric has found a unique balance of efficient and redundant interactions in their architecture. This balance implies that highly efficient ecosystems tend to be inflexible and vulnerable to perturbations while highly redundant ecosystems fail to utilize resources effectively for survival. Motivated by this unique architectural property of ecosystems, this study investigates the response to disruptions vs. affordability trade-space of a large number of feasible SoS architectures. Results indicate that the most favorable SoS architectures in this trade-space share a specific range of values of Degree of System Order. This suggests that Degree of System Order can be a key metric in engineered SoS development. Evaluating the Degree of System Order does not require detailed simulations and can, therefore, guide the early stage SoS design process towards more optimal SoS architectures.
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