Production of coffee beans is an important lifeline for the economy of several countries in Latin America, Africa, and Asia. The brew from this well sought for cash crop is readily consumed due to its good sensory qualities owing to the presence of many micronutrients. Some of these chemical compounds possess biological activities, including antiproliferative, antioxidant, and antimicrobial effects. Four representative groups of these micronutrients, namely, caffeine, chlorogenic acid, diterpenes, and trigonelline, play key roles in these bioactive effects of coffee. In order to guarantee the quality of coffee products and to protect consumer interest and safeguard their well-being, it is extremely important to employ sensitive and accurate analytical methods in the characterization and quantitative determination of these bioactive constituents. This review aims to present recent applications in this regard.

Cyanobacteria are aquatic and photosynthetic organisms known for their rich pigments. They are extensively employed as food supplements due to their rich contents of proteins. While many species, such asAnabaenasp., produce hepatotoxins (e.g., microcystins and nodularins) and neurotoxins (such as anatoxin a),Spirulina (Arthrospira)displays anticancer and antimicrobial (antibacterial, antifungal, and antiviral) activities via the production of phycocyanin, phycocyanobilin, allophycocyanin, and other valuable products. This paper is an effort to collect these nutritional and medicinal applications ofArthrospirain an easily accessible essay from the vast literature on cyanobacteria.

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A sensitive and accurate method for the determination of two model phenoxy herbicides, 4-chloro-2-methylphenoxy acetic acid and 4-chloro-2-methylphenoxy propanoic acid, in water is explained. This method utilizes a simple phase transfer catalyst-assisted microextraction with simultaneous derivatization. Factors affecting the performance of this method including pH of the aqueous matrix, temperature, extraction duration, type and amount of derivatization reagents, and type and amount of the phase transfer catalyst are examined. Derivatization and the use of phase transfer catalyst have proven to be especially vital for the resolution of the analytes and their sensitive determination, with an enrichment factor of 288-fold for catalyzed over noncatalyzed procedure. Good linearity ranging from 0.1 to 80 μg L(-1) with correlation of determination (r(2) ) between 0.9890 and 0.9945 were obtained. Previous reported detection limits are compared with our new current method. The low LOD for the two analytes (0.80 ng L(-1) for 4-chloro-2-methylphenoxy propanoic acid and 3.04 ng L(-1) for 4-chloro-2-methylphenoxy acetic acid) allow for the determination of low concentrations of these analytes in real samples. The absence of matrix effect was confirmed through relative recovery calculations. Application of the method to seawater and tap water samples was tested, but only 4-chloro-2-methylphenoxy propanoic acid at concentrations between 0.27 ± 0.01 and 0.84 ± 0.06 μg L(-1) was detected in seawater samples.