Anion passivation effect on metal-oxide nano-architecture offers a highly controllable platform for improving charge selectivity and extraction, with direct relevance to their implementation in hybrid solar cells. In current work, we demonstrated the incorporation of fluorine (F) as an anion dopant to address the defect-rich nature of ZnO nanorods (ZNR) and improve the feasibility of its role as electron acceptor. The detailed morphology evolution and defect engineering on ZNR were studied as a function of F-doping concentration (x). Specifically, the rod-shaped arrays of ZnO were transformed into taper-shaped arrays at high x. A hypsochromic shift was observed in optical energy band gap due to the Burstein-Moss effect. A substantial suppression on intrinsic defects in ZnO lattice directly epitomized the novel role of fluorine as an oxygen defect quencher. The results show that 10-FZNR/P3HT device exhibited two-fold higher power conversion efficiency than the pristine ZNR/P3HT device, primarily due to the reduced Schottky defects and charge transfer barrier. Essentially, the reported findings yielded insights on the functions of fluorine on (i) surface –OH passivation, (ii) oxygen vacancies (Vo) occupation and (iii) lattice oxygen substitution, thereby enhancing the photo-physical processes, carrier mobility and concentration of FZNR based device.
Controllable growth of metal sulfide-metal oxide based nanomaterial with tunable band gap structure plays a vital role in new generation optoelectronics devices. In this paper, twodimensional hierarchical CdS/ZnO nanorods arrays were successfully grown via low temperature hydrothermal-SILAR method. A concise mechanism related to the surface and band gap modification on the CdS/ZnO nanorods was investigated under the various CdS deposition cycle (N). The diameter and surface roughness properties of the sample were found to be linearly dependent on the N. A bathochromic shift in optical energy band gap revealed the quantum size effects of the CdS/ZnO nanorods as well as the induced interface band state and energy band split in ZnO band state. An impressive improvement in crystallinity of the sample was also observed under the CdS treatment. The correlation between the optical band gap and photovoltaic efficiency was evaluated. The results proved that ZnO nanorods/CdS QDs devices exhibited threefold higher power conversion efficiency in comparison to pristine ZnO nanorods device.
The binary metal oxides show advantages in energy storage devices. Specifically, nickel cobaltite (NiCo2O4) materials showed promising pseudocapacitive properties, high electrical conductivity and large surface area by virtue of their effective porous structure. NiCo2O4 nanosheets were hydrothermally grown in this work over flexible tapes of Aluminum (Al) and Copper (Cu). A nanosheets structure obtained of NiCo2O4 as confirmed by SEM and AFM images. The measured thickness by 3D profilometer of NiCo2O4 nanosheets based Al framework found to be 4.3 µm compared to 8.4 µm thick of film based-Cu framework. Asymmetric supercapacitor prepared from graphite and NiCo2O4 electrodes separated by filter paper. Acidic aqueous electrolyte of H2SO4 and basic aqueous electrolyte of KOH were employed to verify the cyclic activity and electrochemical reaction of asymmetric prepared supercapacitor devices. The basic KOH electrolyte shows a high stability and better charge transfer/ionic diffusion compared to the acidic H2SO4 electrolyte in particular for NiCo2O4 film-based Cu framework. The energy density and power density values were 0.9 W h kg−1 and 66.45 W kg−1, respectively. The highest specific capacity (in F.g−1) = 10.09 coincides with NiCo2O4/Cu supercapacitor in the basic KOH electrolyte. The charge storage in the supercapacitor system of NiCo2O4 and graphite can be ascribed in the form of Faradic charge transfer and capacitive non-faradic double layer, respectively.
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