Organochlorine pesticides are groups of chemicals applied to prevent pest and insect infestation. This study was aimed at investigating the concentration, potential sources, cancer risk and ecological toxicity of organochlorine pesticides (OCPs) in Huangpi district, Wuhan, China. Eight OCPs in soil samples collected from four land-use types at depths of 0–10 and 10–20 cm were examined. Sample extraction was carried out by solid phase matrix extraction method and analyzed using Agilent gas chromatograph 7890B equipped with electron capture detectors (ECD). The total concentration of OCPs ranged from 0.00–32.7 ng g−1 in the surface and 0.01–100.45 ng g−1 in the subsurface soil layer. Beta hexachlorocyclohexanes (β-HCH) with 2.20 and 7.71 ng g−1 in the surface and subsurface soil layers, respectively, was the dominant compound. The mean concentrations of OCPs in all samples were less than the threshold values for hexachlorocyclohexanes (HCHs) and dichlorodiphenyltrichloroethane (DDTs) in China soil. Concentration of OCPs in the four land-use types were in the order of: paddy field > barren land > farmland > plastic greenhouse. Results of composition analysis revealed recent application of lindane as a major and historical use of new technical HCHs as a minor source of HCHs. On the other hand, application of new technical p,p’-DDT is the main source of DDTs in the study area. The estimated lifetime average daily dose, incremental lifetime cancer risks and hazard quotient values revealed that there is less likelihood of carcinogenic and noncarcinogenic health risks on the local residents.
Polycyclic aromatic hydrocarbons are large groups of ubiquitous environmental pollutants composed of two or more fused aromatic rings. This study was designed to evaluate the distribution, potential sources, and ecological and cancer risks of eleven polycyclic aromatic hydrocarbons from Huangpi soils in Wuhan, central China. The soil samples for this study were taken from 0–10 cm and 10–20 cm soil depths. A modified matrix solid-phase dispersion extraction method was applied to extract analytes from the soil samples. A gas chromatograph equipped with a flame ionization detector was used to determine the concentrations of the compounds. The sum mean concentrations of the polycyclic aromatic hydrocarbons were 138.93 and 154.99 µg kg−1 in the 0–10 cm and 10–20 cm soil depths, respectively. Benzo[a]pyrene and fluorene were the most abundant compounds in the 0–10 cm and 10–20 cm soil depths, respectively. The quantitative values of the pyrogenic index, total index, and diagnostic ratio used in this study showed that the polycyclic aromatic hydrocarbons have a pyrogenic origin. The negligible and maximum permissible concentrations values for naphthalene, acenaphthylene, acenaphthene, phenanthrene, anthracene, pyrene, benz[a]anthracene, and benzo[a]pyrene indicated a moderate ecological risk. The incremental lifetime cancer risk values for adults and children showed a low and moderate cancer risk, respectively.
Species specific allometric equations are important for estimation and quantification of net volume and aboveground biomass of living trees. This study was basically focused on fitting total volume and aboveground biomass models for Juniperus procera plantations in Wondo Genet, Sidama Zone, Ethiopia. Data for fitting the total volume and aboveground biomass models were obtained by destructively sampling of trees from the ten diameter classes of the Juniperus procera plantation in the study area. A total of one hundred ten and fifty-one trees were destructively sampled to fit six total volume and six aboveground biomass models respectively. After important measurements of parameters have completed, model performance evaluation and selecting of best fit models were undertaken using standard error of estimates (SEE), coefficient of determination (R 2), bias (B) and mean of the absolute value of errors (MAE). Accordingly, the total volume model Vt = −5.466 + 0.959Dbh 0.005 H 003 and aboveground biomass model of B = 0.348Dbh 0.57 H 0.032 were found to be the best predictive models for total tree volume and aboveground biomass respectively. In addition to the above results, diameter at breast height and total tree height data obtained from 69 circular sample plots of 0.01 ha area drawn from the plantation were used to estimate the total volume and aboveground biomass per hectare BEF which was estimated to be 0.64 Mg/m 3. Generally, the selected models and computed BEF in this study are believed to be applied by different organisations and researches to estimate the total volume and aboveground biomass of the J. procera.
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