Cross cyclotetramerization of trans-2,3-diphenylbutanedinitrile with 1,2,5-thia(selena)diazole-3,4-dicarbonitriles or phthalodinitrile in the presence of magnesium butoxide gave mixtures of Mg(II) porphyrazine complexes which were treated with trifluoroacetic acid to isolate unsymmetrical hexaphenyl-substituted 1,2,5-thia(selena)diazolo-and benzo-fused porphyrazines together with diphenyltribenzoporphyrazine. Their 1H NMR and electronic absorption spectra (in the UV and visible regions) were recorded. The effect of benzene and heteroring fusion on the electronic and steric structure and spectral properties of porphyrazine derivatives was studied in terms of the molecular orbital perturbation theory and semiempirical quantum-chemical calculations (AM1, PM3, ZINDO/S, CNDO/S)
2008 Porphyrin derivatives R 0130 Synthesis and Spectral Properties of 1,2,5-Thiadiazolo-, 1,2,5-Selenadiazolo-, and Benzo-Fused β-Phenyl-Substituted Porphyrazines. -(STUZHIN*, P. A.; PIMKOV, I. V.; UL'-KHAK, A.; IVANOVA, S. S.; POPKOVA, I. A.; VOLKOVICH, D. I.; KUZ'MITSKII, V. A.; DONZELLO, M.-P.; Russ.
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