γ-Al2O3 is a porous metal oxide and described as a defective spinel with some cationic vacancies. In this work, we calculate the electronic density of states and band structure for the bulk of this material. The calculations are performed within the density functional theory using the full potential augmented plan waves plus local orbital method, as embodied in the WIEN2k code. We show that the modified Becke-Johnson exchange potential, as a semi-local method, can predict the bandgap in better agreement with the experiment even compared to the accurate but much more expensive green function method. Moreover, our electronic structure analysis indicates that the character of the valence band maximum mainly originates from the p orbital of those oxygen atoms that are close to the vacancy. The charge density results show that the polarization of the oxygen electron cloud is directed toward aluminum cations, which cause Al and O atoms to be tightly connected by a strong dipole bond.
The photoluminescence emission of nanoporous anodic aluminum oxide films formed in phosphoric acid is studied in order to explore their defect-based subband electronic structure. Different excitation wavelengths are used to identify most of the details of the subband states. The films are produced under different anodizing conditions to optimize their emission in the visible range. Scanning electron microscopy investigations confirm pore formation in the produced layers. Gaussian analysis of the emission data indicates that subband states change with anodizing parameters, and various point defects can be formed both in the bulk and on the surface of these nanoporous layers during anodizing.
Here, a generalized induction coil sensor model (more generalized than other models) has been considered at low frequencies (within 0.1-100 Hz), and the equivalent magnetic field of the coil's thermal noise and the sensor's signal to noise ratio (SNR) were calculated theoretically based on the dimensions and geometry of the coil winding and its core. In our suggested theoretical consideration, all involved parameters were considered and optimized without any assumption and constraint, while some authors in their latest reports, have been used some assumptions and constraints in their sensor calculations (such as holding constant the sensor's volume and aspect ratio). Our calculations indicated that the equivalent magnetic field of the thermal noise can be minimized by the coil to core weight ratio. Moreover, it was found that the sensor's SNR can be maximized with only a special value of core aspect ratio (length to diameter of core ratio). The obtained theoretical results were evaluated experimentally by fabricating a search coil magnetometer model, using the optimum parameters. The resonance frequency and the parasitic capacitance of the coil were measured. Moreover, variations of the transfer function of the magnetometer, with respect to frequency, were studied. Thus, it was shown that, at low frequencies, our experimentally measured noise data exhibit better agreement with our suggested theoretical results with respect to the state of the art.
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