Compositional, frequency, and temperature studies of impedance and electrical conductivity in (Ag3AsS3)x(As2S3)1−x superionic glasses and composites were performed. Frequency range from 10 Hz to 3 × 109 Hz and temperature interval 300–400 K were used for the measurements. Compositional dependences of electrical conductivity and activation energy are analyzed; the most substantial changes are observed with the transition from (Ag3AsS3)0.4(As2S3)0.6 glass to (Ag3AsS3)0.5(As2S3)0.5 composite. With increase of Ag3AsS3 content, the investigated materials are found to have crystalline inclusions and show the two-phase composite nature. Addition of Ag3AsS3 leads to the increase of electrical conductivity whereas the activation energy decreases.
Absolute cross sections for K-shell ionization of free metal atoms K, Ca, Rb and Sr by electrons with energies up to 45 keV have been measured with uncertainty 15% using a crossed-beams technique. The results are compared with other measurements for free atoms and theoretical calculations.
Optical absorption spectra of x-ray irradiated CdS1−xSex nanocrystals embedded in a borosilicate glass matrix are studied. The observed transformation of the confinement-related features in the spectra is related to the x-ray-induced negative ionization of the nanocrystals with charge transfer across the nanocrystal/matrix interface. The radiation-induced changes and their relaxation upon postirradiation storage as a function of nanocrystal size and composition are discussed.
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