The aim for this work is to investigate the effect of alkaline treatment on the mechanical, physical and thermal properties of roselle (RF)/sugar palm fiber (SPF) reinforced thermoplastic polyurethane hybrid composites. RF/SPF hybrid composites were fabricated at different NaOH concentrations (3%, 6% and 9%) by melt mixing and compression molding. The mechanical, physical and thermal properties of RF/SPF hybrid composites were measured. The morphological properties of the tensile fractured sample were examined using scanning electron microscope. Obtained results indicated that the effect of NaOH treatment on the surface improved mechanical, physical and thermal properties accompanied by lower impact resistance. The highest tensile is 14.26 MPa, flexural strength is 14.05 MPa and impact strength is 23.76 kJ/M2) was obtained from treatment 6% NaOH concentration on RF/SPF hybrid composites. Adhesion bonding between fiber and matrix was evident by using Scanning electron microscopy (SEM) micrograph of hybrid composite tensile fractured. Scanning electron micrograph of tensile fractured surfaces of the NaOH treated RF/SPF hybrid composites revealed good adhesion bonding between fiber and matrix. Fourier transform infrared spectroscopy analysis was used to observe the effectiveness of NaOH treatment in the removal impurities on fiber surfaces. Thermogravimetric analysis showed that the treated RF/SPF hybrid composites had improved the thermal stability. Physical properties showed lower water uptake of the treated thermoplastic polyurethane hybrid composites. The lowest water uptake is 7.97% and thickness swelling is 6.49% obtained from 9% NaOH concentration after soaked in water for 7 days. Overall, the surface treatment on RF/SPF hybrid composite has enhanced the composite properties and suitable for automotive part application; battery holder and bottom based.
The aim of this paper is to study the effect of fibre content on mechanical and morphological properties and thermal stability of roselle fibres (RFs) reinforced polyurethane (TPU) composites. The RF/TPU composites were prepared at difference fibre contents; 10, 20, 30, 40 and 50 wt% by melt mixed mixer and hot press at 170 °C. Mechanical (tensile, flexural and impact strength) and Thermogravimetric analysis (TGA) properties of RF/TPU composites were measured according to ASTM standard. Obtained results indicated that effect of fibre contents display improved tensile and flexural and impact strength properties. RF/TPU composites show the best mechanical and thermal properties at 40 wt% roselle fibre content. Scanning electron microscopy (SEM) micrograph of fractured tensile sample of the roselle composite revealed good fibre/matrix bonding. TGA showed that RF/TPU with difference fibre contents had improved thermal stability.
Natural-fiber-reinforced composites, especially bamboo, are an alternative material to compete with conventional materials. Their environmentally friendly, renewable, low-cost, low-density, non-toxic, and fully biodegradable properties are concerning for researchers because of their advantages over synthetic polymers. This comprehensive review presents the results of work on bamboo fiber composites with special reference to bamboo types, thermoplastic and thermoset polymers matrices, hybrid composites, and their applications. In addition, several studies prove that these properties are very good and efficient in various applications. However, in the development of composite technology, bamboo fiber has certain constraints, especially in moisture conditions. Moisture is one of the factors that reduces the potential of bamboo fiber and makes it a critical issue in the manufacturing industry. Therefore, various efforts have been made to ensure that these properties are not affected by moisture by treating the surface fibers using chemical treatments.
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